Abstract
The work presents research data on the optical properties of nanosized particles of silver, gold, rhodium and ruthenium prepared by chemical reduction of the Men+ ions in inverse micellar solutions (IMS) in the presence of molecular oxygen and the flavonoid reducer quercetin. Metallic nanoparticles and the bimetallic particles Au/Ag, Au/Ru, and Au/Rh were produced by the molecule-by-molecule method. Using UV–VIS spectrophotometry, the spectral characteristics of the monometallic and bimetallic nanoparticles were examined, and the kinetics of their formation in IMS was studied.
Similar content being viewed by others
REFERENCES
A. O. Kucherik, S. V. Kutrovskaya, A. V. Osipov, et al., Izv. YuFU, Tekh. Nauki, No. 9, 101 (2015).
L. V. Shapoval, T. B. Boitsova, V. V. Gorbunova, A. Yu. Vakhrushev, and T. A. Arkhipova, Russ. J. Gen. Chem. 11, 290 (2011).
M. O. Sergeev, A. Yu. Antonov, A. A. Revina, et al., Usp. Khim. Khim. Tekhnol. 26 (7), 33 (2012).
K. F. Chernyshova and A. A. Revina, Kondens. Sredy Mezhfaz. Granitsy 20, 296 (2018). https://doi.org/10.17308/kcmf.2018.20/521
S. P. Turanskaya, A. D. Chetyrkin, I. V. Dubrovin, et al., Poverkhnost’, No. 3, 343 (2011).
N. K. Eremenko, V. G. Dodonov, Yu. A. Zakharov, I. I. Obraztsova, and A. N. Eremenko, Vestn. Kemer. Univ. 3 (3), 189 (2014).
A. A. Revina, RF Patent No. 2312741, Byull. Izobret., No. 35 (2007).
B. H. Robinson, A. N. Khan-Lodhi, and T. Towey, in Structure and Reactivity in Reverse Micelles, Ed. by M.-P. Pileni (Elsevier, Amsterdam, New York, Toronto, 1989)), p. 199.
M. P. Pileni, Langmuir 13, 3266 (1997).
C. G. M. Heijnen, G. R. M. M. Haenen, F. A. A. van Acker, W. J. F. van Der, and A. Bast, Toxicol. Vitro 15, 3 (2001).
D. Metodiewa, A. K. Jaiswal, N. Cenas, E. Dickancaite, and J. Segura-Aguilar, Free Radical Biol. Med. 26, 107 (1999).
K. F. Chernyshova and A. A. Revina, Naukoemk. Tekhnol. 18 (1), 45 (2017).
O. V. Dement’eva, A. V. Mal’kovskii, M. A. Filippenko, and V. M. Rudoy, Colloid. J. 70, 561 (2008).
C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983).
M. Kerker, The Scattering of Light and Other Electromagnetic Radiation (Academic, New York, 1969), p. 38.
B. G. Ershov, Zh. Ros. Khim. Ob-va im. D. I. Mendeleeva 45 (3), 20 (2001).
U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters (Springer, Berlin, 1995).
A. Yu. Antonov, O. A. Boeva, A. A. Revina, and K. F. Nurtdinova, Persp. Mater. Spets. Vyp., No. 10, 268 (2011).
M. O. Sergeev, O. A. Boeva, and K. N. Zhavoronkova, Usp. Khim. Khim. Tekhnol. 28 (6), 122 (2014).
A. F. Shoair, A. A. El-Bindary, and M. K. Abd El-Kader, J. Mol. Struct., No. 1143, 100 (2017). https://doi.org/10.1016/j.molstruc.2017.03.109
A. A. Revina, Prot. Met. Phys. Chem. Surf. 45, 54 (2009).
P. G. Kuzmin, G. A. Shafeev, A. V. Simakin, and V. V. Voronov, Phys. Wave Phenom. 16, 261 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by E. Khozina
Rights and permissions
About this article
Cite this article
Chernysheva, K.F., Revina, A.A. Formation and Stabilization of Au, Ag, Ru, and Rh Metallic and Bimetallic Nanoparticles in Inverse Micellar Solutions. Russ. J. Phys. Chem. B 13, 452–457 (2019). https://doi.org/10.1134/S1990793119030023
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1990793119030023