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Hydrogen bond and exchange interaction in the (CuSO4)(en)·2H2O and (CuSO4)(en)·2D2O organometallic compounds

  • Structure of Chemical Compounds. Spectroscopy
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Abstract

The influence of the replacement of hydrogen with deuterium in molecules of water of crystallization in the structure of the (CuSO4)(en) · 2H2O and (CuSO4)(en)·2D2O organometallic compound molecules on exchange interaction between copper ions was studied. The X-ray structural data and the data on angular anisotropy of the effective g-factor of Cu2+ ions in both compounds show that distortions of the initial structure caused by deuteration are minimum. A comparative analysis of the width of the exchange coupled EPR lines of the two compounds is indicative of a decrease in the exchange parameter in the deuterated sample, which substantiates the participation of H-bonds in exchange interactions in the systems studied.

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Authors and Affiliations

  1. Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, Kharkov, 61103, Ukraine

    O. V. Kravchina, A. I. Kaplienko & E. P. Nikolova

  2. Karazin Kharkov National University, Kharkov, 61077, Ukraine

    A. G. Anders & D. V. Ziolkovskii

  3. Department of Experimental Physics, Faculty of Science, P. J. Safarik University, Park Angelinum 9, 04154, Kosice, Slovakia

    A. Orendachova & M. Kajnakova

Authors
  1. O. V. Kravchina
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  2. A. I. Kaplienko
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  3. E. P. Nikolova
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  4. A. G. Anders
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  5. D. V. Ziolkovskii
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  6. A. Orendachova
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  7. M. Kajnakova
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Corresponding author

Correspondence to A. I. Kaplienko.

Additional information

Original Russian Text © O.V. Kravchina, A.I. Kaplienko, E.P. Nikolova, A.G. Anders, D.V. Ziolkovskii, A. Orendachova, M. Kajnakova, 2011, published in Khimicheskaya Fizika, 2011, Vol. 30, No. 3, pp. 24–30.

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Kravchina, O.V., Kaplienko, A.I., Nikolova, E.P. et al. Hydrogen bond and exchange interaction in the (CuSO4)(en)·2H2O and (CuSO4)(en)·2D2O organometallic compounds. Russ. J. Phys. Chem. B 5, 209–214 (2011). https://doi.org/10.1134/S1990793111020205

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  • DOI: https://doi.org/10.1134/S1990793111020205

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