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New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates)

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Abstract

Crosslinked polysiloxanes with boron bis(dibenzoylmethanate) complexes used as crosslink junctions of polymer networks are first synthesized, and their physicochemical, mechanical, thermal, and fluorescent properties are studied. It is shown that the polymers under study feature the elastic behavior, possess high thermal and thermo-oxidative stability, and exhibit intense fluorescence in a wide wavelength range (400‒700 nm).

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Funding

This work was supported by the Russian Science Foundation (project no. 18-73-10152). Characterization of compounds by NMR spectroscopy, TGA, and DSC performed using equipment of the Center for Molecule Composition Studies at the Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences was supported by the Ministry of Science and Higher Education of the Russian Federation (contract no. 075-03-2023-642). Luminescence lifetimes were measured using equipment of the Center for Collective Use “Structural Diagnostics of Materials” within the framework of State Assignment for the Federal National Research Center “Crystallography and Photonics,” Russian Academy of Sciences.

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russia

    E. E. Kim, T. M. Il’ina, Yu. N. Kononevich, D. A. Khanin, G. G. Nikiforova & A. M. Muzafarov

  2. Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

    T. M. Il’ina

  3. Photochemistry Center, Federal National Research Center “Crystallography and Photonics,” Russian Academy of Sciences, 119421, Moscow, Russia

    D. S. Ionov

  4. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    A. M. Muzafarov

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  1. E. E. Kim
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  3. Yu. N. Kononevich
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  7. A. M. Muzafarov
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Correspondence to Yu. N. Kononevich.

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Translated by T. Soboleva

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Kim, E.E., Il’ina, T.M., Kononevich, Y.N. et al. New Fluorescent Materials Based on Polysiloxanes and Boron Bis(β-diketonates). Polym. Sci. Ser. C 65, 267–276 (2023). https://doi.org/10.1134/S1811238223700376

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  • DOI: https://doi.org/10.1134/S1811238223700376

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