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Organosilicon Comb-Shaped Surfactants for the Synthesis of Polymer Suspensions with a Narrow Particle Size Distribution

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Abstract

The polymerization of styrene in the presence of an organosilicon comb-shaped surfactant, α,ω‑bis(trimethylsiloxy)-oligodimethylmethyl-(10-carboxydecyl)siloxane, is studied. The reaction yields aggregatively stable polystyrene suspensions with a polymer content of up to 50%, a high surface concentration of carboxyl groups, and a particle diameter of up to 2.2 μm. A comparative analysis of the kinetic regularities of polymerization and the properties of polymer suspensions in the presence of the comblike, dimeric, and linear surfactants is carried out.

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ACKNOWLEDGMENTS

This work was performed using the equipment of the Collaborative Access Center for Polymer Research, Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 19-33-60053, and the Ministry of Science and Higher Education of the Russian Federation.

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Authors and Affiliations

  1. Russian Technological University (MIREA), 119571, Moscow, Russia

    A. A. Ezhova, I. A. Gritskova, M. A. Lazov & S. N. Chvalun

  2. Federal Scientific and Clinical Center for Physical and Chemical Medicine, Federal Medical and Biological Agency, 119435, Moscow, Russia

    S. A. Gusev

  3. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, 117393, Moscow, Russia

    S. A. Milenin, V. V. Gorodov & A. M. Muzafarov

  4. National Research Center Kurchatov Institute, 123182, Moscow, Russia

    S. N. Chvalun

Authors
  1. A. A. Ezhova
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  2. I. A. Gritskova
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  4. S. A. Milenin
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  6. A. M. Muzafarov
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  8. S. N. Chvalun
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Correspondence to A. A. Ezhova.

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Ezhova, A.A., Gritskova, I.A., Gusev, S.A. et al. Organosilicon Comb-Shaped Surfactants for the Synthesis of Polymer Suspensions with a Narrow Particle Size Distribution. Polym. Sci. Ser. B 63, 209–217 (2021). https://doi.org/10.1134/S1560090421030052

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  • DOI: https://doi.org/10.1134/S1560090421030052

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