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Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges

  • Functional Polymers
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Abstract

The structure of zirconocene is determined experimentally. Zirconocene is found to catalyze effectively the copolymerization of α-olefins with nonconjugated dienes in the presence of minimal amounts of methylalumoxane as an organoaluminum activator. On the basis of a highly ferromagnetic carrier (a product of the reaction between Fe3O4 microparticles and Si(OEt)4), a deposited zirconocene catalyst is obtained. Using the latter, copolymers of α-olefins (1-hexene, 1-octene, and 1-decene) with 1,7-octadiene and 1,4- di(3-butenyl)benzene are synthesized. The obtained ferromagnetic copolymers demonstrate properties of effective absorbents of hydrocarbons, namely, oil sponges. A copolymer of 1-octene and 1,4-di(3-butenyl) benzene is found to possess the maximum adsorption capacity (up to 8) in the studied series.

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Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Leninskii pr. 29, Moscow, 119991, Russia

    P. V. Ivchenko, I. E. Nifant’ev, A. A. Vinogradov & G. A. Shandryuk

  2. Department of Chemistry, Moscow State University, Moscow, 119991, Russia

    P. V. Ivchenko, I. E. Nifant’ev & D. P. Krut’ko

Authors
  1. P. V. Ivchenko
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  2. I. E. Nifant’ev
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  3. A. A. Vinogradov
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  4. D. P. Krut’ko
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  5. G. A. Shandryuk
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Correspondence to P. V. Ivchenko.

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Original Russian Text © P.V. Ivchenko, I.E. Nifant’ev, A.A. Vinogradov, D.P. Krut’ko, G.A. Shandryuk, 2017, published in Vysokomolekulyarnye Soedineniya, Seriya B, 2017, Vol. 59, No. 1, pp. 71–79.

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Ivchenko, P.V., Nifant’ev, I.E., Vinogradov, A.A. et al. Crosslinked α-olefin-diene copolymers prepared using a metallocene catalyst deposited on the surface of SiO2-modified Fe3O4: Ferromagnetic oil sponges. Polym. Sci. Ser. B 59, 83–90 (2017). https://doi.org/10.1134/S1560090417010079

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  • DOI: https://doi.org/10.1134/S1560090417010079

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