Skip to main content
SpringerLink
Log in

Synthesis and characterization of a novel silane-based vinylic monomer and its application in the multilayer core-shell latex

  • Synthesis
  • Published:
Polymer Science Series B Aims and scope Submit manuscript

Abstract

A novel monomer methacrylamidophenoxy dimethylsiloxy phenylphthalimide was obtained by a reaction of 4,4′-bis-aminophenoxy dimethylsilane, phthalic anhydride and methacryloyl chloride. Then it has been used in the synthesis of phase-separated polymer latex with a multilayer core-shell morphology by surface cross-linking emulsion polymerization. Poly(butyl acrylate) was used for the seed and the core of the latex, the inner shell was poly(butyl acrylate/styrene) cross-linked with divinylbenzene to avoid phase inversion, and the poly(methyl methacrylate/butyl acrylate/methacrylamidophenoxy dimethylsiloxy phenylphthalimide) was the outer shell. The structural elucidation of monomer was carried out by elemental analysis, FTIR, 1H NMR, and 13C NMR spectroscopic techniques. The morphology and glass transition temperatures of the synthesized product were investigated by transmission electron microscopy and differential scanning calorimetry, respectively. The multilayer core-shell structure was clearly shown in TEM micrographs, and the three-phase separation was confirmed by DSC analysis. The obtained results demonstrated that the average particle size is 81.8, 108 and 132 nm for the core, core-shell and multilayer core-shell particles, which agrees with the TEM micrograph measurement of 75, 103, and 131 nm, respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Guo, X. Chen, M. Song, and B. Zhang, J. Appl. Polym. Sci. 100, 1824 (2006).

    Article  CAS  Google Scholar 

  2. S. S. Cao, B. L. Liu, X. B. Deng, and S. J. Li, Macromol. Biosci. 5, 669 (2005).

    Article  CAS  Google Scholar 

  3. F. Bauer, H. J. Gläsel, U. Decker, H. Ernst, A. Freyer, E. Hartmann, V. Sauerland, and R. Mehnert,, Prog. Org. Coat. 47, 147 (2003).

    Article  CAS  Google Scholar 

  4. H. J. Naghash, A. Karimzadeh, and A. R. Massah, J. Appl. Polym. Sci. 112, 1037 (2009).

    Article  CAS  Google Scholar 

  5. H. J. Naghash, A. Karimzadeh, A. R. Massa, and H. Alian, Turk. J. Chem. 31, 257 (2007).

    CAS  Google Scholar 

  6. B. L. Liu, X. B. Deng, S. S. Cao, S. J. Li, and R. Luo, Appl. Surf. Sci. 252, 2235 (2006).

    Article  CAS  Google Scholar 

  7. H. J. Naghash and R. Mohammadrahimpanah, Prog. Org. Coat. 70, 32 (2011).

    Article  CAS  Google Scholar 

  8. H. J. Naghash and B. Abili, Prog. Org. Coat. 69, 486 (2010).

    Article  CAS  Google Scholar 

  9. J. S. Turner and Y. L. Cheng, Macromolecules 33, 3714 (2000).

    Article  CAS  Google Scholar 

  10. B. L. Liu, B. T. Zhang. S. S. Cao, X. B. Deng, X. Hou, and H. Chen, Prog. Org. Coat. 61, 21 (2008).

    Article  CAS  Google Scholar 

  11. S. Zaioncz, K. Dahmouche, C. M. Paranhos, R. A. S. Gil, and B. G. Soares, Polym. Lett. 3, 340 (2009).

    CAS  Google Scholar 

  12. M. R. Moghbeli and S. Tolue, Iran. Polym. J. 20, 137 (2011).

    CAS  Google Scholar 

  13. C. W. Lin and W. L. Lee, J. Appl. Polym. Sci. 70, 383 (1998).

    Article  CAS  Google Scholar 

  14. J. Van den Brand, O. Blajiev, P. C. J. Beentjes, H. Terryn, and De J. H. W. Wit, Langmuir 20, 6308 (2004).

    Article  Google Scholar 

  15. Y. Zhang, Q. Jin, J. Zhao, C. Wu, Q. Fan, and Q. Wu, Eur. Polym. J. 46, 1425 (2010).

    Article  CAS  Google Scholar 

  16. L. Fedrizzi, A. Bianchi, F. Deflorian, S. Rossi, and P. L. Bonora, Electrochim. Acta 47, 2159 (2002).

    Article  CAS  Google Scholar 

  17. X. Zhou, G. E. Thompson, and G. M. Scamans, Corros. Sci. 45, 1767 (2003).

    Article  CAS  Google Scholar 

  18. M. G. Olivier, M. Poelman, M. Demuynck, and J. P. Petitjean, Prog. Org. Coat. 52, 263 (2005).

    Article  CAS  Google Scholar 

  19. Z. M. Chen, S. J. Pan, H. J. Yin, L. L. Zhang, E. C. Ou, Y. Q. Xiong, and W. Xu, EXPRESS Polym. Lett. 5, 38 (2011).

    Article  CAS  Google Scholar 

  20. N. S. Sangaj and V. C. Malshe, Prog. Org. Coat. 50, 28 (2004).

    Article  CAS  Google Scholar 

  21. Q. S. Yu and H. K. Yasuda, Prog. Org. Coat. 52, 217 (2005).

    Article  CAS  Google Scholar 

  22. W. J. Soer, W. Ming, B. Klumperman, C. Koning, and R. Benthem, Polymer 47, 7621 (2006).

    Article  CAS  Google Scholar 

  23. C. X. Sun, M. A. J. Van der Mee, J. G. P. Goossens, and M. Van Duin, Macromolecules 39, 3441 (2006).

    Article  CAS  Google Scholar 

  24. J. Sherman, L. Robert, and W. T. Ford, Ind. Eng. Chem. Res. 44, 8538 (2005).

    Article  CAS  Google Scholar 

  25. A. Aguiar, V. S. Gonzalez, M., M. Rabelero, E. Mendizabal, and J. E. Puig, Macromolecules 32, 6767 (1999).

    Article  CAS  Google Scholar 

  26. A. R. Mahdavian, M. Ashjari, and H. S. J. Mobarakeh, J. Appl. Polym. Sci. 110, 1242 (2008).

    Article  CAS  Google Scholar 

  27. Y. Zhao, H. Wang, Y. Liu, J. Ye, and S. Shen, Mater. Lett. 62, 4254 (2008).

    Article  CAS  Google Scholar 

  28. J. Jonsson, O. J. Karlsson, H. Hassander, and B. Tornell, Eur. Polym. J. 43, 1322 (2007).

    Article  Google Scholar 

  29. W. Liu, R. Zheng, and Z. He, Polym. Bull. (Berlin) 61, 27 (2008).

    Article  CAS  Google Scholar 

  30. Y. F. Chen, E. M. Woo, and W. Pi-Ling, Mater. Lett. 61, 4911 (2007).

    Article  CAS  Google Scholar 

  31. D. Colombini, N. Ljungberg, H. Hassander, and O. J. Karlsson, Polymer 46, 1295 (2005).

    Article  CAS  Google Scholar 

  32. X. Xinyan and L. Jianfei, Chin. J. Chem. Eng. 16, 626 (2008).

    Article  Google Scholar 

  33. H. J. Adler, K. Jahny, and B. Vogt-Birnbrich, Prog. Org. Coat. 43, 251 (2001).

    Article  CAS  Google Scholar 

  34. S. Spiegel, K. Landfester, G. Lieser, C. Boeffel, S. H. Wolfgang, and N. Eidam, Macromol. Chem. Phys. 196, 985 (1995).

    Article  CAS  Google Scholar 

  35. H. Yu, J. Peng, M. Zhai, J. Li, G. Wei, and J. Qiao, Radiat. Phys. Chem. 76, 1746 (2007).

    Article  CAS  Google Scholar 

  36. S. H. Kim, W. K. Son, Y. J. Kim, E. Kang, and D. W. Kim, J. Appl. Polym. Sci. 88, 595 (2003).

    Article  CAS  Google Scholar 

  37. J. Jonsson, H. Hassander, L. H. Jansson, and B. Tornell, Macromolecules 24, 126 (1991).

    Article  Google Scholar 

  38. S. Kirsch, A. Doerk, E. Bartsch, H. Sillescu, K. Landfester, and H. Spiess, Macromolecules 32, 4508 (1999).

    Article  CAS  Google Scholar 

  39. L. J. Gonzalez-Ortiz and J. M. Asua, Macromolecules 29, 4520 (1996).

    Article  CAS  Google Scholar 

  40. K. Landfester and H. W. Spiess, Acta Polym. 49, 451 (1998).

    Article  CAS  Google Scholar 

  41. C. F. Lee, Y. H. Chen, and W. Y. Chiu, J. Appl. Polym. Sci. 69, 13 (1998).

    Article  CAS  Google Scholar 

  42. W. D. He and C. Y. Pan, Chin. J. Appl. Chem. 13, 8 (1996).

    Google Scholar 

  43. B. T. Zhang, B. L. Liu, S. S. Cao, and X. B. Deng, Chin. Leath. 11, 53 (2007).

    Google Scholar 

  44. S. Y. Cheng, Y. J. Chen, and Z. G. Chen, J. Appl. Polym. Sci. 85, 1147 (2002).

    Article  CAS  Google Scholar 

  45. C. Y. Kan, D. S. Liu, and X. Z. Kong. J. Appl. Polym. Sci. 82, 3194 (2001).

    Article  CAS  Google Scholar 

  46. S. Q. Huang, Z. S. Xu, H. Peng, and S. Y. Cheng, J. Appl. Polym. Sci. 71, 2209 (1999).

    Article  CAS  Google Scholar 

  47. W. D. He, C. T. Cao, and C. Y. Pan, J. Appl. Polym. Sci. 61, 383 (1996).

    Article  CAS  Google Scholar 

  48. A. Kierys, M. Dziadosz, and J. Goworek, J. Colloid Interface Sci. 349, 361 (2010).

    Article  CAS  Google Scholar 

  49. X. Cui, S. Zhong, J. Yan, C. Wang, H. Zhang, and H. Wang, Colloids Surf. A 360, 41 (2010).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Shahreza Branch, Islamic Azad University, P.O. Box 311-86145, Shahreza, Isfahan, Iran

    Hamid Javaherian Naghash & Feyzollah Shafie

Authors
  1. Hamid Javaherian Naghash
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Feyzollah Shafie
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hamid Javaherian Naghash.

Additional information

The article is published in the original.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Naghash, H.J., Shafie, F. Synthesis and characterization of a novel silane-based vinylic monomer and its application in the multilayer core-shell latex. Polym. Sci. Ser. B 55, 620–633 (2013). https://doi.org/10.1134/S1560090413130022

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1560090413130022

Keywords

Search

Navigation