Skip to main content
SpringerLink
Log in

Influence of Xerogel Synthesis Conditions in the ZrO2–Y2O3–CeO2 System on the Properties of Powders and Ceramics Based on Them

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

Xerogels in the ZrO2–Y2O3–CeO2 system are obtained by coprecipitation. The influence of the synthesis method on the acid-base xerogel surface properties are studied. The sinuous dependence of the Lewis and Brønsted site content on the particle surface on the conditioning time of precipitates in the mother liquor and the presence of subsequent low-temperature processing is established. The relationship is established between the resulting ceramics properties, precipitate processing conditions, and the functional xerogel structure.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. Gevorkyan, E.S., Mel’nik, O.M., Chishkala, V.A., and Sirota, V.V., Phase and structural process in nanocrystalline powders based on zirconia dioxide, Ogneupory Tekh. Keram., 2012, nos. 7–8, pp. 26–31.

  2. Popov, V.V. and Petrunin, V.F., Investigating the formation processes and stability of metastable phase in nanocrystalline ZrO2, Ogneupory Tekh. Keram., 2007, no. 8, pp. 8–13.

  3. Dudnik, E.V., Shevchenko, A.V., Ruban, A.K., Red’ko, V.P., and Lopato, L.M., Effect of Al2O3 on the properties of nanocrystalline ZrO2 + 3 mol % Y2O3 powder, Inorg. Mater., 2010, vol. 46, no. 2, pp. 172–176.

  4. Antsiferov, V.N., Porozova, S.E., Kul’met’eva, V.B., and Torsunov, M.F., Phase composition of nanodisperse zirconia powders stabilized by yttria and ceria, Ogneupory Tekh. Keram., 2012, no. 4-5, pp. 17–21.

  5. Shevchenko, A.V., Lashneva, V.V., Dudnik, E.V., Ruban, A.K., and Podzorova, L.I., Nanosist., Nanomater., Nanotekhnol., 2011, vol. 9, no. 4, pp. 881–893.

  6. Lukin, E.S., Modern high-density oxide ceramics with the controlled microstructure. Pt. 1. Oxide powder aggregation effect on the ceramics sintering and microstructure, Ogneupory Tekh. Keram., 1996, no. 1, pp. 5–12.

  7. Lin, J.-D. and Duh, J.-G., Correlation of mechanical properties and composition in tetragonal CeO2–Y2O3–ZrO2 ceramic system, Mater. Chem. Phys., 2002, no. 78, pp. 246–252.

  8. Kravchik, K.V., Gomza, Yu.P., Pashkova, O.V., Belous, A.G., and Nesin, S.D., Effect of zirconium and yttrium hydroxide precipitation conditions on the fractal structure of the resulting xerogels and 0.97ZrO2 · 0.03Y2O3 powders, Inorg. Mater., 2007, vol. 43, no. 3, pp. 258–263.

    Article  CAS  Google Scholar 

  9. Vasserman, I.M., Khimicheskoe osazhdenie iz rastvorov (Chemical Deposition from Solutions), Leningrad: Khimiya, 1980.

  10. Kul’met’eva, V.B., Porozova, S.E., and Gnedina, E.S., Synthesis of nanocrystalline yttrium oxide stabilized zirconia for low temperature sintering, Izv. Vyssh. Uchebn. Zaved., Poroshk. Metall. Funkts. Pokryt., 2011, no. 2, pp. 3–9.

  11. Ivanova, E.A. and Konakov, V.G., Problems of powde-precursor agglomeration of system ZrO2–HfO2–Y2O3, Vestn. SPbGU, Ser. 4, 2007, no. 2, pp. 106–110.

  12. Koval’ko, N.Yu., Kalinina, M.V., Maslennikova, T.P., Morozova, L.V., Myakin, S.V., Khamova, T.V., Arsent’ev, M.Yu., and Shilova, O.A., Comparative study of powders based on the ZrO2–Y2O3–CeO2 system obtained by various liquid phase methods of synthesis, Glass Phys. Chem., 2018, vol. 44, no. 5, pp. 433–439.

  13. Petrunin, V.F., Popov, V.V., Zhu, Hongzhi, and Timofeev, A.A., Synthesis of nanocrystalline high-temperature zirconia phases, Inorg. Mater., 2004, vol. 40, no. 3, pp. 251–258.

    Article  CAS  Google Scholar 

  14. Antsiferov, V.N. and Makarova, E.N., Study of ultrasonic treatment and pre-wetting in ethanol on ZrO2–Y2O3–CeO2–Al2O3 nanopowders size distribution and agglomeration degree, Perspekt. Mater., 2015, no. 1, pp. 41–48.

  15. Porozova, S.E., Vokhmyanin, D.S., and Kul’met’eva, V.B., Some features nanopowders compacting zirconia, Ogneupory Tekh. Keram., 2013, no. 9, pp. 10–14.

  16. Panova, T.I., Arsent’ev, M.Yu., Morozova, L.V., and Drozdova, I.A., Synthesis and investigation of the structure of ceramic nanopowders in the ZrO2–CeO2–Al2O3 system, Glass Phys. Chem., 2010, vol. 36, no. 4, pp. 470–477.

    Article  CAS  Google Scholar 

  17. Morozova, L.V., Panova, T.I., Drozdova, I.A., and Shilova, O.A., Features of the production of nanoceramics based on stabilized zirconia for various functional purposes, Perspekt. Mater., 2011, no. S13, pp. 561–568.

  18. Gvetadze, R.Sh., D’yakonenko, E.E., and Lebedenko, I.Yu., The study of aging, fatigue and degradation for the purpose of improving the reliability of dental Zirconia ceramics. A review of articles in world’s journals, Stomatologiya, 2016, no. 6, pp. 51–60.

  19. Koval'ko, N.Yu., Kalinina, M.V., Malkova, A.N., Lermontov, S.A., Morozova, L.V., Polyakova, I.G., and Shilova, O.A., Synthesis and comparative studies of xerogels, aerogels, and powders based on the ZrO2–Y2O3–CeO2 system, Glass Phys. Chem., 2017, vol. 43, no. 4, pp. 368–375.

    Article  CAS  Google Scholar 

  20. Morozova, L.V., Kalinina, M.V., Koval’ko, N.Yu., Arsent’ev, M.Yu., and Shilova, O.A., Preparation of zirconia-based nanoceramics with a high degree of tetragonality, Glass Phys. Chem., 2014, vol. 40, no. 3, pp. 352–355.

    Article  CAS  Google Scholar 

  21. Sychev, M.M., Minakova, T.S., Slizhov, Yu.G., and Shilova, O.A., Kislotno-osnovnye kharakteristiki poverkhnosti tverdykh tel i upravlenie svoistvami materialov i kompozitov (Acid-Base Characteristics of the Surface of Solids and Control of the Properties of Materials and Composites), St. Petersburg: Khimizdat, 2016.

  22. Nechiporenko, A.P., Donorno-aktseptornye svoistva poverkhnosti tverdofaznykh sistem. Indikatornyi metod (Donor-Acceptor Surface Properties of Solid-Phase Systems. Indicator Method), St. Petersburg: Lan’, 2017.

  23. GOST (State Standard) 21216-2014: Clay Raw Materials. Test Methods, Moscow: Standartinform, 2015.

  24. GOST (State Standard) 473.4-81: Chemically Resistant and Heat Resistant Ceramic Wears. The Method for Determination of Apparent Density and Apparent Sponginess, Moscow: Standartinform, 1981.

  25. GOST (State Standard) 9450-76: Measurements of Microhardness by Diamond Instruments Indentation, Moscow: Standartinform, 1976.

  26. Irodov, I.E., Volnovye protsessy (Wave Processes), Moscow: Lab. Bazov. Znanii, 2003.

  27. Generalov, M.B., Kriokhimicheskaya nanotekhnologiya: Ucheb. posobie dlya vuzov (Cryochemical Nanotechnology: A Textbook), Moscow: Akademkniga, 2006.

Download references

Funding

This work was partially supported by the Russian Science Foundation (project no. 19-13-00442).

Author information

Authors and Affiliations

  1. Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

    N. Yu. Fedorenko, A. S. Dolgin, N. A. Khristyuk, I. G. Polyakova, M. V. Kalinina & O. A. Shilova

  2. St. Petersburg State Institute of Technology (Technical University), 190013, St. Petersburg, Russia

    S. V. Myakin, V. M. Frank, A. S. Dolgin & O. A. Shilova

  3. St. Petersburg Electrotechnical University LETI, 197376, St. Petersburg, Russia

    O. A. Shilova

Authors
  1. N. Yu. Fedorenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Myakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. M. Frank
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. S. Dolgin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N. A. Khristyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. I. G. Polyakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. M. V. Kalinina
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. O. A. Shilova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. Yu. Fedorenko.

Additional information

Translated by A. Kolemesin

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fedorenko, N.Y., Myakin, S.V., Frank, V.M. et al. Influence of Xerogel Synthesis Conditions in the ZrO2–Y2O3–CeO2 System on the Properties of Powders and Ceramics Based on Them. Glass Phys Chem 46, 176–180 (2020). https://doi.org/10.1134/S1087659620020030

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1087659620020030

Keywords:

Search

Navigation