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Template synthesis of CMK-3 nanostructured carbon material and study of its properties

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Abstract

Mesostructured carbon has been obtained by template synthesis. SBA-15 mesostructured silicate has been used as a template. The effect of the properties of a template on the ordering of a replica has been studied. It has been shown with the use of X-ray diffraction, gas adsorption, and electron microscopy that there are evident correlations of the conditions of synthesis of a template with the ordering of a carbon replica, which can be guided by the synthesis of materials. The ordering of a replica significantly depends on the mesopore volume of the initial template and thickness of the pore wall. One should use templates with the highest possible mesopore volume and minimal wall thickness to obtain highly ordered replicas. These templates can be prepared during the treatment of synthesized materials at temperatures close to 100°C. It has been determined that, when there is SBA-15, the presence of micropores is a necessary condition for the preparation of carbon replicas that retain the structure of the template.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Engineering, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50/24, Krasnoyarsk, 660036, Russia

    I. V. Ponomarenko, V. A. Parfenov, Yu. N. Zaitseva & S. D. Kirik

  2. Siberian Federal University, pr. Svobodnyi 79, Krasnoyarsk, 660049, Russia

    S. M. Zharkov & S. D. Kirik

Authors
  1. I. V. Ponomarenko
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  2. V. A. Parfenov
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  3. Yu. N. Zaitseva
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  4. S. M. Zharkov
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  5. S. D. Kirik
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Correspondence to I. V. Ponomarenko.

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Original Russian Text © I.V. Ponomarenko, V.A. Parfenov, Yu.N. Zaitseva, S.M. Zharkov, S.D. Kirik, 2014, published in Fizika i Khimiya Stekla.

Published from the Proceedings of the II International Conference of the CIS “Sol-Gel Synthesis and Study of Inorganic Compounds, Hybrid Functional Materials, and Disperse Systems,” held in Sevastopol’, Ukraine, on September, 18–20, 2012.

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Ponomarenko, I.V., Parfenov, V.A., Zaitseva, Y.N. et al. Template synthesis of CMK-3 nanostructured carbon material and study of its properties. Glass Phys Chem 40, 79–87 (2014). https://doi.org/10.1134/S1087659614010180

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