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Enthalpies of mixing of two alkali glasses and glasses containing alkali and alkaline-earth cations

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Abstract

The enthalpy of mixing of silicate glasses containing Na, K, and Ba cations is estimated using differential thermal analysis. It is shown that the interaction of sodium silicate and potassium silicate glasses with barium silicate glass is an endothermic process, whereas the interaction of sodium silicate glass with potassium silicate glass is an exothermic process.

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References

  1. Belyustin, A.A. and Shultz, M.M., Interdiffusion and Accompanying Processes in Surface Layers of Alkali Silicate Glasses treated with Aqueous Solutions, Fiz. Khim. Stekla, 1983, vol. 9, no. 1, pp. 3–27.

    CAS  Google Scholar 

  2. Smirnova, N.A., Molekulyarnye teorii rastvorov (Molecular Theories of Solutions), Leningrad: Khimiya, 1987 [in Russian].

    Google Scholar 

  3. Takashi, K. and Yoshio, T., Heats of Mixing in Mixed Alkali Glasses, Zairyo Kagaku (J. Soc. Mater. Sci. Jpn.), 1977, vol. 26, no. 287, pp. 785–790.

    Google Scholar 

  4. Rogez, J. and Mathieu, J.-C., Entalpie de Formation dans le Systeme Na2O-K2O-SiO2, Phys. Chem. Liq., 1985, vol. 14, no. 14, pp. 259–271.

    Article  CAS  Google Scholar 

  5. Choudary, U.V., Gaskell, D.R., and Belton, G.R., Thermodynamics of Mixing in Molten Sodium-Potassium Silicates at 1100°C: The Effect of a Calcium Oxide Addition, Metall. Trans. B, 1977, vol. 8, no. 1, pp. 67–71.

    Article  Google Scholar 

  6. Kassis, N. and Frischat, G.H., Dampfdrücke von Glasschmelzen des Mischalkalisystems Na2O-Rb2O-SiO2, Glastech. Ber., 1981, vol. 54, no. 4, pp. 89–98.

    CAS  Google Scholar 

  7. Garfinkel, H.T., Ion-Exchange Equilibria between Glass and Molten Salts, J. Phys. Chem., 1968, vol. 72, no. 12, pp. 4175–4181.

    Article  CAS  Google Scholar 

  8. Śestak, J., Thermophysical Properties of Solids: Their Measurements and Theoretical Thermal Analysis, Prague: Academia, 1984. Translated under the title Teoriya termicheskogo analiza: Fizikokhimicheskie svoistva tverdykh neorganicheskikh veshchestv, Moscow: Mir, 1987.

    Google Scholar 

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, St. Petersburg, 199034, Russia

    S. I. Sviridov, Z. G. Tyurnina & N. G. Tyurnina

Authors
  1. S. I. Sviridov
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  2. Z. G. Tyurnina
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  3. N. G. Tyurnina
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Correspondence to S. I. Sviridov.

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Original Russian Text © S.I. Sviridov, Z.G. Tyurnina, N.G. Tyurnina, 2008, published in Fizika i Khimiya Stekla.

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Sviridov, S.I., Tyurnina, Z.G. & Tyurnina, N.G. Enthalpies of mixing of two alkali glasses and glasses containing alkali and alkaline-earth cations. Glass Phys Chem 34, 634–636 (2008). https://doi.org/10.1134/S1087659608050155

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  • DOI: https://doi.org/10.1134/S1087659608050155

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