Skip to main content
SpringerLink
Log in

Dependences of the dilatometric properties of glasses on their structure: II. Silicate, phosphate, fluorine-containing, and titanium-containing glasses

  • Published:
Glass Physics and Chemistry Aims and scope Submit manuscript

Abstract

The dependences of the dilatometric properties on the hypothetical structure for a number of silicate, phosphate, fluorine-containing, and other glasses are analyzed over a wide range of compositions. Special attention is focused on the behavior of the structural temperature coefficient of linear expansion. It is demonstrated that the revealed regularities allow the justified inferences regarding structural transformations of glasses with variations in their composition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Klyuev, V.P., Dependence of the Dilatometric Properties of Glasses on Their Structure: 1. Borate, Aluminoborate, and Lead-Containing Glasses, Fiz. Khim. Stekla, 2005, vol. 31, no. 6, pp. 1028–1042 [Glass Phys. Chem. (Engl. transl.), 2005, vol. 31, no. 6, pp. 749–759].

    Google Scholar 

  2. Hagy, H.E., Experimental Evaluation of Beam-Bending Method of Determining Glass Viscosities in the Range 108–1015 Poises, J. Am. Ceram. Soc., 1963, vol. 46, no. 2, pp. 93–102.

    CAS  Google Scholar 

  3. Dietzel, A., Zusammenhang zwischen Ausdehnungkoeffizient und Struktur von Gläser, Glastech. Ber., 1941, vol. 19, no. 10, pp. 319–325.

    CAS  Google Scholar 

  4. Hurt, J.C. and Phillips, C.J., Structural Role of Zinc Oxide in Glasses in the System Na2O-ZnO-SiO2, J. Am. Ceram. Soc., 1970, vol. 53, no. 5, pp. 269–273.

    CAS  Google Scholar 

  5. Takahashi, K., Mochida, N., Matsui, H., Takeuchi, S., and Gohshi, Y., Properties and Structure of Glasses in the Systems SiO2-PO2.5 and GeO2-PO2.5, J. Ceram. Soc. Jpn., 1986, vol. 84, no. 10, pp. 482–490.

    Google Scholar 

  6. Schultz, P.C., US Patent 4 042 404, 1977.

  7. Jabra, R., Phallipou, J., and Zarzicky, J., Synthesis of Binary Glass-Forming Oxide Glasses by Hot-Pressing of Gels, J. Non-Cryst. Solids, 1980, vol. 42, nos. 1–3, pp. 489–498.

    CAS  Google Scholar 

  8. Demskaya, E.L., Komarova, L.A., and Prokhorova, T.I., Investigation into Features of Synthesis and Properties of Glasses in the P2O5-SiO2 System, Fiz. Khim. Stekla, 1989, vol. 15, no. 4, pp. 579–583.

    CAS  Google Scholar 

  9. Klyuev, V.P. and Mal’shikov, A.E., Synthesis and Properties of Glasses in the P2O5-SiO2 System, Fiz. Khim. Stekla, 1989, vol. 15, no. 5, pp. 746–749.

    CAS  Google Scholar 

  10. Klyuev, V.P., Karov, D.D., and Rusan, V.V., Viscosity and Thermal Expansion in the Glass Transition Range of Glasses Based on Metaphosphates and Ultraphosphates, Tezisy konferentsii “Stroenie, svoistva i primenenie fosfatnykh, ftoridnykh i khal’kogenidnykh stekol” (Abstracts of Papers, Conference “Structure, Properties, and Application of Phosphate, Fluoride, and Chalcogenide Glasses”), Riga, 1990, pp. 49–50.

  11. Brückner, R., Charakteristische physikalische Eigenschaften der oxydischen Hauptglasbildner und ihre Beziehung zur Struktur der Gläser, Glastech. Ber., 1964, vol. 37, no. 10, pp. 459–475.

    Google Scholar 

  12. Brow, R.K., Nature of Alumina in Phosphate Glass: I. Properties of Sodium Aluminophosphate Glass, J. Am. Ceram. Soc., 1993, vol. 76, no. 4, pp. 913–918.

    CAS  Google Scholar 

  13. Appen, A.A., Khimiya stekla (The Chemistry of Glasses), Leningrad: Khimiya, 1970.

    Google Scholar 

  14. Rawson, H., Inorganic Glass-Forming Systems, New York: Academic, 1967. Translated under the title Neorganisheskie stekloobrazuyushchie sistemy, Moscow: Mir, 1970.

    Google Scholar 

  15. Plyshevskii, S.V., Soklakov, A.I., Kuz’menkov, M.I., and Pechkovskii, V.V., Investigation into the Structure of Vitreous Aluminum Metaphosphate, Neorg. Mater., 1977, vol. 13, no. 2, pp. 325–328.

    CAS  Google Scholar 

  16. Brow, R.K., Kirkpatrick, R.J., and Turner, G.L., Nature of Alumina in Phosphate Glass: II. Structure of Sodium Aluminophosphate Glass, J. Am. Ceram. Soc., 1993, vol. 76, no. 4, pp. 919–928.

    CAS  Google Scholar 

  17. Nemilov, S.V. and Volkova, N.E., The Viscosity of K2O-P2O5-Al2O3 Glasses in the Softening and Annealing Temperature Range, Fiz. Khim. Stekla, 1992, vol. 18, no. 6, pp. 88–96. [Sov. J. Glass Phys. Chem. (Engl. transl.), 1992, vol. 18, no. 6, pp. 452–456].

    CAS  Google Scholar 

  18. Schultz, P.C. and Mizzoni, M.S., Anionic Conductivity in Halogen-Containing Lead Silicate Glasses, J. Am. Ceram. Soc., 1973, vol. 56, no. 2, pp. 65–68.

    CAS  Google Scholar 

  19. Coon, J. and Shelby, J.E., Properties and Structure of Lead Fluorosilicate Glasses, J. Am. Ceram. Soc., 1988, vol. 71, no. 5, pp. 354–357.

    Article  CAS  Google Scholar 

  20. Orlova, M.A. and Khalilev, V.D., Glass Formation and Properties of Glasses in the PbSiO3-PbF2(PbO)-AlF3(AlO1.5) System, Fiz. Khim. Stekla, 1984, vol. 10, no. 2, pp. 245–247.

    CAS  Google Scholar 

  21. Khodakovskaya, R.Ya., Khimiya titansoderzhashchikh stekol i sitallov (Chemistry of Titanium-Containing Glasses and Glass Ceramics), Moscow: Khimiya, 1978.

    Google Scholar 

  22. Liška, M., Klyuev, V.P., Antalík, J., and Štubňa, I., Thermodilatometry and Structural Relaxation of Na2O · 2SiO2-Na2O · 2TiO2 Glasses, Ceram. Silik., 1996, vol. 40, no. 3, pp. 81–87.

    Google Scholar 

  23. Liška, M., Klyuev, V.P., Antalík, J., and Štubňa, I., Viscosity of Na2O · 2(TiO2, SiO2) Glasses, Phys. Chem. Glasses, 1997, vol. 38, no. 1, p. 6.

    Google Scholar 

  24. Klyuev, V.P., Hübert, Th., Banach, U., Kirch, M., and Bulaeva, A.V., Effect of Titanium Dioxide on the Properties of Strontium Aluminoborate Glasses, Proceedings of the XV International Congress on Glass, Leningrad: Nauka, 1989, vol. 2b, pp. 341–344.

    Google Scholar 

  25. Hübert, Th., Banach, U., Witke, K., and Reich, P., Structural Studies of Glasses in the System SrO-B2O3-Al2O3-TiO2, Phys. Chem. Glasses, 1991, vol. 32, no. 2, pp. 58–66.

    Google Scholar 

  26. Klyuev, V.P. and Pevzner, B.Z., Influence of Aluminum and Gallium Oxides on the Thermal Expansion and Viscosity of Barium Borate Glasses, Fiz. Khim. Stekla, 1998, vol. 24, no. 4, pp. 532–545 [Glass Phys. Chem. (Engl. transl.), 1998, vol. 24, no. 4, pp. 372–381].

    Google Scholar 

  27. Klyuev, V.P. and Pevzner, B.Z., The Influence of Aluminum Oxide on the Thermal Expansion, Glass Transition Temperature, and Viscosity of Lithium and Sodium Aluminoborate Glasses, Fiz. Khim. Stekla, 2002, vol. 28, no. 4, pp. 295–314 [Glass Phys. Chem. (Engl. transl.), 2002, vol. 28, no. 4, pp. 207–220].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, ul. Odoevskogo 24/2, St. Petersburg, 199155, Russia

    V. P. Klyuev

Authors
  1. V. P. Klyuev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © V.P. Klyuev, 2006, published in Fizika i Khimiya Stekla.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Klyuev, V.P. Dependences of the dilatometric properties of glasses on their structure: II. Silicate, phosphate, fluorine-containing, and titanium-containing glasses. Glass Phys Chem 32, 196–205 (2006). https://doi.org/10.1134/S108765960602012X

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S108765960602012X

Keywords

Search

Navigation