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Synthesis of 1,3-Bis(3-R-adamantan-1-yl)acetones

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Abstract

Methods have been developed for the synthesis of symmetrical 1,3-bis(3-R-adamantan-1-yl)­acetones [R = OH, aryl, heteroaryl, R′C(O)NH, NH2C(S)NH] by CF3SO3H/(CF3CO)2O-catalyzed self-acylation of 2-(3-hydroxyadamantan-1-yl)acetic acid.

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Funding

This study was performed according to the state program “Petrochemistry and Catalysis. Rational Use of Carbon-Containing Raw Materials” (project no. 121031300092-6).

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    V. V. Kovalev & E. A. Shokova

Authors
  1. V. V. Kovalev
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  2. E. A. Shokova
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Correspondence to V. V. Kovalev.

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The authors declare the absence of conflict of interest.

Additional information

Translated from Zhurnal Organicheskoi Khimii, 2022, Vol. 58, No. 1, pp. 61–68 https://doi.org/10.31857/S0514749222010050.

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Kovalev, V.V., Shokova, E.A. Synthesis of 1,3-Bis(3-R-adamantan-1-yl)acetones. Russ J Org Chem 58, 47–53 (2022). https://doi.org/10.1134/S1070428022010055

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  • DOI: https://doi.org/10.1134/S1070428022010055

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