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Novel Fe3O4/SiO2/PPA Magnetic Nanoparticles: Preparation, Characterization, and First Catalytic Application to the Solvent- Free Synthesis of Tetrahydrobenzo[a]xanthene-11-ones

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Abstract

Novel Fe3O4/SiO2/PPA nanoparticles were used as solid acid support in the solvent-free synthesis of 12-aryl-9,9-dimethyl-8,9,10,12-tetrahydro-11H-benzo[a]xanthen-11-ones via multicomponent condensation of aromatic aldehydes with naphthalen-2-ol and 5,5-dimethylcyclohexane-1,3-dione. The target products were obtained in good to high yields. The Fe3O4/SiO2/PPA nanoparticles were thoroughly characterized by scanning electron microscopy, transmission electron microscopy, Fourier-transform IR spectroscopy, and energy-dispersive C-ray spectroscopy. The new catalyst has a high activity and is environmentally friendly, heterogeneous, easily recoverable, and recyclable without loss of catalytic activity.

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Acknowledgments

The authors are sincerely grateful to the spiritual and financial support of the Islamic Azad University of Neyshabour Branch.

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Authors and Affiliations

  1. Department of Chemistry, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    F. Amarloo & R. Zhiani

  2. New Material Technology and Processing Research Center, Chemistry Department, Neyshabur Branch, Isalamic Azad University, Neyshabur, Iran

    R. Zhiani

  3. Department of Biochemistry, Neyshabur Branch, Islamic Azad University, Neyshabur, Iran

    J. Mehrzad

Authors
  1. F. Amarloo
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  2. R. Zhiani
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  3. J. Mehrzad
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Correspondence to R. Zhiani.

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Amarloo, F., Zhiani, R. & Mehrzad, J. Novel Fe3O4/SiO2/PPA Magnetic Nanoparticles: Preparation, Characterization, and First Catalytic Application to the Solvent- Free Synthesis of Tetrahydrobenzo[a]xanthene-11-ones. Russ J Org Chem 55, 1584–1590 (2019). https://doi.org/10.1134/S1070428019100191

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  • DOI: https://doi.org/10.1134/S1070428019100191

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