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Reaction of Potassium 1,1,3,3-Tetracyano-2-(2,2-dimethylpropanoyl)propenide with 2-Sulfanylethanol

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Abstract

The reaction of potassium 2-(2,2-dimethylpropanoyl)-1,1,3,3-tetracyanopropenide with an equimolar amount of 2-sulfanylethanol afforded 2-{5-amino-2-(tert-butyl)-4-cyano-2-[(2-hydroxyethyl)sulfanyl]- 2,3-dihydrofuran-3-ylidene}propanedinitrile, whereas 4-amino-1-(tert-butyl)-1,6-bis[(2-hydroxyethyl)- sulfanyl]-3-imino-1,3-dihydrofuro[3,4-c]pyridine-7-carbonitrile was obtained in the reaction with excess 2-sulfanylethanol.

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Authors and Affiliations

  1. I.N. Ul’yanov Chuvash State University, Moskovskii pr. 15, Cheboksary, 428015, Russia

    A. A. Grigor’ev, S. V. Karpov, O. E. Nasakin & Ya. S. Kayukov

  2. Faculty of Chemistry, Moscow State University, Leninskie gory 1, Moscow, 119991, Russia

    V. A. Tafeenko

  3. Chuvash State Agricultural Academy, ul. Karla Marksa 29, Cheboksary, 428003, Russia

    O. V. Kayukova

Authors
  1. A. A. Grigor’ev
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  2. S. V. Karpov
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  3. O. E. Nasakin
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  4. V. A. Tafeenko
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  5. O. V. Kayukova
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  6. Ya. S. Kayukov
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Corresponding author

Correspondence to Ya. S. Kayukov.

Additional information

Original Russian Text © A.A. Grigor’ev, S.V. Karpov, O.E. Nasakin, V.A. Tafeenko, O.V. Kayukova, Ya.S. Kayukov, 2018, published in Zhurnal Organicheskoi Khimii, 2018, Vol. 54, No. 3, pp. 496–498.

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Grigor’ev, A.A., Karpov, S.V., Nasakin, O.E. et al. Reaction of Potassium 1,1,3,3-Tetracyano-2-(2,2-dimethylpropanoyl)propenide with 2-Sulfanylethanol. Russ J Org Chem 54, 503–505 (2018). https://doi.org/10.1134/S107042801803020X

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  • DOI: https://doi.org/10.1134/S107042801803020X

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