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(4S,6R)-4-methyl-6-pentyltetrahydro-2H-pyran-2-one as an efficient intermediate in the preparation of chiral building blocks with methyl-branched carbon skeleton. Application to the synthesis of bioactive compounds

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Abstract

Synthesis was performed of (3S)-3-methyldecen-1-ol and (4S)-4-methylundecen-1-ol, chiral alcohols with a methyl-branched carbon skeleton. The possibility of their application in asymmetric syntheses of insect pheromones was demonstrated.

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Authors and Affiliations

  1. Belarusian State University, pr. Nezavisimosti 4, Minsk, 220030, Belarus

    I. V. Mineyeva, V. S. Masyuk & V. N. Kovalenko

  2. M. Tank Belarusian State Pedagogical University, Minsk, Belarus

    V. N. Kovalenko & M. M. Bandarenko

Authors
  1. I. V. Mineyeva
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  2. V. S. Masyuk
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  3. V. N. Kovalenko
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  4. M. M. Bandarenko
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Correspondence to I. V. Mineyeva.

Additional information

Original Russian Text © I.V. Mineyeva, V.S. Masyuk, V.N. Kovalenko, M.M. Bandarenko, 2014, published in Zhurnal Organicheskoi Khimii, 2014, Vol. 50, No. 11, pp. 1635–1641.

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Mineyeva, I.V., Masyuk, V.S., Kovalenko, V.N. et al. (4S,6R)-4-methyl-6-pentyltetrahydro-2H-pyran-2-one as an efficient intermediate in the preparation of chiral building blocks with methyl-branched carbon skeleton. Application to the synthesis of bioactive compounds. Russ J Org Chem 50, 1621–1627 (2014). https://doi.org/10.1134/S1070428014110141

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  • DOI: https://doi.org/10.1134/S1070428014110141

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