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Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium

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Abstract

The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymethyloxirane with 2-propanol under conditions of phase-transfer catalysis the main product was the corresponding 1,2-diol (yield 42%).

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References

  1. Matuszczak, S. and Feast, W. J., J. Fluorine Chem., 2000, vol. 102, p. 269.

    Article  CAS  Google Scholar 

  2. Solov’ev, D.V., Kolomenskaya, L.V., Rodin, A.A., Zenkevich, I.G., and Lavrent’ev, A.N., Zh. Obshch. Khim., 1991, 61, p. 673.

    CAS  Google Scholar 

  3. Ushakova, E.N., Konyushko, O.V., Glazkov, A.A., and Krukovskii, S.P., Izv. Akad. Nauk, Ser. Khim., 1996, p. 1573.

  4. Petrov, V.A., J. Fluorine Chem., 2004, vol. 125, p. 531.

    Article  CAS  Google Scholar 

  5. Host Guest Complex Chemistry: Macrocycles: Synthesis, Structures, Applications, Vogtle, F. and Weber, E., Eds., Berlin: Springer, 1985.

    Google Scholar 

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, Yekaterinburg, 620219, Russia

    D. N. Bazhin, T. I. Gorbunova, A. Ya. Zapevalov, V. E. Kirichenko & V. I. Saloutin

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  1. D. N. Bazhin
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  2. T. I. Gorbunova
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  3. A. Ya. Zapevalov
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  4. V. E. Kirichenko
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  5. V. I. Saloutin
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Original Russian Text © D.N. Bazhin, T.I. Gorbunova, A.Ya. Zapevalov, V.E. Kirichenko, V.I. Saloutin, 2007, published in Zhurnal Organicheskoi Khimii, 2007, Vol. 43, No. 5, pp. 661–664.

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Bazhin, D.N., Gorbunova, T.I., Zapevalov, A.Y. et al. Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium. Russ J Org Chem 43, 656–659 (2007). https://doi.org/10.1134/S1070428007050041

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  • DOI: https://doi.org/10.1134/S1070428007050041

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