Abstract
Destruction of the methylene blue dye in aqueous solutions by liquid-phase peroxide oxidation in the presence of MeFe2O4 catalysts (Me = Mn, Co, Mg, Cu) supported on various types of cellulose was studied. The textural and acidic properties of the catalysts were tested. The specific surface area of the catalysts was found to be 68–256 m2 g–1, MeFe2O4 is the main phase of the catalysts, and the acidity of aqueous suspensions of catalysts is in the region of a neutral and slightly alkaline media (pH 7.3–9.4). Among the tested catalysts, the most efficient were MnFe2O4/microcrystalline cellulose (CMC) and MgFe2O4/cotton cellulose hydrolyzed (CCH). Their use gives 98% methylene blue conversion for 3 h of reaction time. The high efficiency of the MnFe2O4/CMC and MgFe2O4/CMC catalysts is apparently attributable to the high specific surface area provided by the microcrystalline cellulose support and the low ionization potential of Mg and Mn in the structure of the substitutional solid oxide.
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Translated from Zhurnal Prikladnoi Khimii, No. 5, pp. 488–497, August, 2023 https://doi.org/10.31857/S0044461823050067
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Tregubova, K.V., Mishchenko, T.I., Gurovskii, V.V. et al. Utilization of Methylene Blue by Liquid-Phase Peroxide Oxidation in the Presence of Catalysts Based on Transition Metal Oxides and Cellulose. Russ J Appl Chem 96, 552–561 (2023). https://doi.org/10.1134/S1070427223050063
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DOI: https://doi.org/10.1134/S1070427223050063