Abstract
Thermodynamic and kinetic aspects of the carbon dioxide reforming of methane are considered. Data on the types of catalytic systems used and on specific features of the commercial implementation of the process are systematized. The optimum temperature and pressure ranges for the carbon dioxide reforming of methane are 700–900°C and 2–4 MPa, respectively. Detailed analysis of the published data on the activity and stability of dry reforming catalysts shows that the key factor influencing the activity of the catalysts and their resistance to coking is the balance between the properties of the support and composition of the active metal phase. For example, the acid–base properties of the support determine the strength of binding of the metal with the surface, which can influence both the catalyst activity and its stability by preventing sintering of the active component particles. The most widely supports are silicon and aluminum oxides and zirconium and titanium silicates. Their acidity is controlled by introducing doping additives such as cerium, calcium, and magnesium oxides. Both base transition (Ni and Co) and noble (Rh, Ru, Pd, Pt, and Ir) metals as well as bimetallic systems containing sites of both types can serve as an active phase. The main problem restricting the practical use and scaling of the carbon dioxide reforming of methane is catalyst deactivation due to support coking and sintering of the active component particles.
Similar content being viewed by others
Notes
United Nations Framework Convention on Climate Change (UNFCCC). Adoption of the Paris Agreement. FCCC/CP/2015/L.9/Rev.1. 2015.
Publication permission from Elsevier of May 18, 2020.
Publication permission from Royal Society of Chemistry of May 19, 2020.
Publication permission from Springer Letters of May 19, 2020.
Publication permission from Elsevier of May 19, 2020.
Publication permission from Elsevier of May 19, 2020.
Publication permission from Elsevier of May 19, 2020.
Publication permission from American Chemical Society of May 19, 2020.
Publication permission from John Wiley and Sons of May 19, 2020.
REFERENCES
Sokolov, S., Kondratenko, E.V., Pohl, M.M., Barkschat, A., and Rodemerck, U., Appl. Catal. B: Environmental, 2012, vols. 113–114, pp. 19–30. https://doi.org/10.1016/j.apcatb.2011.09.035
Maestri, M., Vlachos, D.G., Beretta, A., Groppi, G., and Tronconi, E., AIChE J., 2009, vol. 55, no. 4, pp. 993–1008. https://doi.org/10.1002/aic.11767
Naidja, A., Krishna, C.R., Butcher, T., and Mahajan, D., Prog. Energy Combust. Sci., 2003, vol. 29, pp. 155–191. https://doi.org/10.1016/S0360-1285(03)00018-2
Olah, G.A., Goeppert, A., Czaun, M., Mathew, T., May, R.B., and Prakash, G.K.S., J. Am. Chem. Soc., 2015, vol. 137, pp. 8720–8729. https://doi.org/10.1021/jacs.5b02029
Yu, M., Zhu, K., Liu, Z., Xiao, H., Deng, W., and Zhou, X., Appl. Catal. B: Environmental, 2014, vol. 148, pp. 177–190. https://doi.org/10.1016/j.apcatb.2013.10.046
Yu, M., Zhu, Y.A., Lu, Y., Tong, G., Zhu, K., and Zhou, X., Appl. Catal. B: Environmental, 2015, vol. 165, pp. 43–56. https://doi.org/10.1016/j.apcatb.2014.09.066
Gould, T.D., Izar, A., Weimer, A.W., Falconer, J.L., and Medlin, J.W., ACS Catal., 2014, vol. 4, pp. 2714–2717. https://doi.org/10.1021/cs500809w
Sternberg, A., Jens, C.M., and Bardow, A., Green Chem., 2017, vol. 19, pp. 2244–2259. https://doi.org/10.1039/c6gc02852g
Ewbank, J.L., Kovarik, L., Kenvin, C.C., and Sievers, C., Green Chem., 2014, vol. 16, pp. 885–896. https://doi.org/10.1039/c3gc41782d
Aramouni, N.A.K., Touma, J.G., Tarboush, B.A., Zeaiter, J., and Ahmad, M.N., Renew. Sustain. Energy Rev., 2018, vol. 82, pp. 2570–2585. https://doi.org/10.1016/j.rser.2017.09.076
Arora, S. and Prasad, R., RSC Adv., 2016, vol. 6, pp. 108668–108688. https://doi.org/10.1039/C6RA20450
Nagaoka, K., Catal. Commun., 2001, vol. 2, pp. 255–260. https://doi.org/10.1016/S1566-7367(01)00043-7
Brungs, A.J., York, A.P.E., Claridge, J.B., Márquez-Alvarez, C., and Green, M.L.H., Catal. Lett., 2000, vol. 70, nos. 3–4, pp. 117–122. https://doi.org/10.1023/A:1018829116093
Wang, S., Lu, G.Q., and Millar, G.J., Energy Fuels, 1996, vol. 10, pp. 896–904. https://doi.org/10.1021/ef950227t
Araujo, G.C., de Lima, S.M., de Assaf, J.M., Peña, M.A., Fierro, J.L.G., and do Carmo Rangel, M., Catal. Today, 2008, vol. 133, pp. 129–135. https://doi.org/10.1016/j.cattod.2007.12.049
Kehres, J., Jakobsen, J.G., Andreasen, J.W., Wagner, J.B., Liu, H., Molenbroek, A., and Vegge, T., J. Phys. Chem. C, 2012, vol. 116, no. 40, pp. 21407–21415. https://doi.org/10.1021/jp3069656
Jang, W.J., Jeong, D.W., Shim, J.O., Kim, H.M., Roh, H.S., Son, I.H., and Lee, S.J., Appl. Eng., 2016, vol. 173, pp. 80–91. https://doi.org/10.1016/j.apenergy.2016.04.006
Nikoo, M.K. and Amin, N.A.S., Fuel Process. Technol., 2011, vol. 92, no. 3, pp. 678–691. https://doi.org/10.1016/j.fuproc.2010.11.027
Li, Y., Wang, Y., Zhang, X., and Mi, Z., Int. J. Hydrogen Energy, 2008, vol. 33, no. 10, pp. 2507–2514. https://doi.org/10.1016/j.ijhydene.2008.02.051
Jang, W.J., Shim, J.O., Kim, H.M., Yoo, S.Y., and Roh, H.S., Catal. Today, 2019, vol. 324, pp. 15–26. https://doi.org/10.1016/j.cattod.2018.07.032
Krylov, O.V., Ross. Khim. Zh., 2000, vol. 46, no. 1, pp. 19–33.
Aboonasr Shiraz, M.H., Rezaei, M., and Meshkani, F., Res. Chem. Intermed., 2016, vol. 42, no. 8, pp. 6627–6642. https://doi.org/10.1007/s11164-016-2485-z
Pakhare, D. and Spivey, J., Chem. Soc. Rev., 2014, vol. 43, no. 22, pp. 7813–7837. https://doi.org/10.1039/c3cs60395d
Tomishige, K., Nurunnabi, M., Maruyama, K., and Kunimori, K., Appl. Catal. A, 2004, vol. 85, p. 1103. https://doi.org/10.1016/j.fuproc.2003.10.014
Izquierdo, U., Barrio, V.L., Requies, J., Cambra, J.F., Güemez, M.B., and Arias, P.L., Int. J. Hydrogen Energy, 2013, vol. 38, no. 18, pp. 7623–7631. https://doi.org/10.1016/j.ijhydene.2012.09.107
Faroldi, B., Bosko, M.L., Múnera, J., Lombardo, E., and Cornaglia, L., Catal. Today, 2013, vol. 213, pp. 135–144. https://doi.org/10.1016/j.cattod.2013.02.024
Pakhare, D., Shaw, C., Haynes, D., Shekhawat, D., and Spivey, J., J. CO2 Util., 2013, vol. 1, pp. 37–42. https://doi.org/10.1016/j.jcou.2013.04.001
Bitter, J.H., Seshan, K., and Lercher, J.A., Top. Catal., 2000, vol. 10, pp. 295–305. https://doi.org/10.1023/A:1019149025242
Wei, J., J. Catal., 2004, vol. 225, no. 1, pp. 116–127. https://doi.org/10.1016/j.jcat.2003.09.030
Hou, Z., Chen, P., Fang, H., Zheng, X., and Yashima, T., Int. J. Hydrogen Energy, 2006, vol. 31, pp. 555–561. https://doi.org/10.1016/j.ijhydene.2005.06.010
Yamaguchi, A. and Iglesia, E., J. Catal., 2010, vol. 274, no. 1, pp. 52–63. https://doi.org/10.1016/j.jcat.2010.06.001
Munera, J., Irusta, S., Cornaglia, L., Lombardo, E., Vargascesar, D., and Schmal, M., J. Catal., 2007, vol. 245, pp. 25–34. https://doi.org/10.1016/j.jcat.2006.09.008
Wang, H.Y. and Ruckenstein, E., J. Phys. Chem. B, 1999, vol. 103, no. 51, pp. 11327–11331. https://doi.org/10.1021/jp992348q
Buyevskaya, O.V., Wolf, D., and Baerns, M., Catal. Lett., 1994, vol. 29, nos. 1–2, pp. 249–260. https://doi.org/10.1007/BF00814271
Nielsen, B., Luntz, A.C., Holmblad, P.M., and Chorkendorff, I., Catal. Lett., 1995, vol. 32, nos. 1–2, pp. 15–30. https://doi.org/10.1007/BF00806098
Zhang, Z. and Verykios, X.E., Catal. Lett., 1996, vol. 38, nos. 3–4, pp. 175–179. https://doi.org/10.1007/BF00806565
Lisi, L., Bagnasco, G., Ciambelli, P., De Rossi, S., Porta, P., Russo, G., and Turco, M., J. Solid State Chem., 1999, vol. 146, no. 1, pp. 176–183. https://doi.org/10.1006/jssc.1999.8327
Ferreira-Aparicio, P., Fernandez-Garcia, M., Guerrero-Ruiz, A., and Rodriguez-Ramos, I., J. Catal., 2000, vol. 190, no. 2, pp. 296–308. https://doi.org/10.1006/jcat.1999.2752
Ruckenstein, E. and Hu, Y.H., Catal. Lett., 1998, vol. 51, pp. 183–185. https://doi.org/10.1023/A:1019030311127
Bradford, M.C. and Albert Vannice, M., Catal. Today, 1999, vol. 50, no. 1, pp. 87–96. https://doi.org/10.1016/S0920-5861(98)00465-9
Lucrédio, A.F., Assaf, J.M., and Assaf, E.M., Appl. Catal. A: General, 2011, vol. 400, nos. 1–2, pp. 156–165. https://doi.org/10.1016/j.apcata.2011.04.035
Erdohelyi, A., J. Catal., 1993, vol. 141, no. 1, pp. 287–299. https://doi.org/10.1006/jcat.1993.1136
Qian, L., Ren, Y., Yu, H., Wang, Y., Yue, B., and He, H., Appl. Catal. A: General, 2011, vol. 401, nos. 1–2, pp. 114–118. https://doi.org/10.1016/j.apcata.2011.05.004
Guo, J., Lou, H., Mo, L., and Zheng, X., J. Mol. Catal. A: Chemical, 2010, vol. 316, nos. 1–2, pp. 1–7. https://doi.org/10.1016/j.molcata.2009.09.023
Van Keulen, A.N.J., Seshan, K., Hoebink, J.H.B.J., and Ross, J.R.H., J. Catal., 1997, vol. 166, no. 2, pp. 306–314. https://doi.org/10.1006/jcat.1997.1539
Tsipouriari, V.A. and Verykios, X.E., Catal. Today, 2001, vol. 64, nos. 1–2, pp. 83–90. https://doi.org/10.1016/S0920-5861(00)00511-3
Wang, H. and Ruckenstein, E., Appl. Catal. A: General, 2000, vol. 204, no. 1, pp. 143–152. https://doi.org/10.1016/S0926-860X(00)00547-0
Ferreira-Aparicio, P., Rodrı́guez-Ramos, I., Anderson, J., and Guerrero-Ruiz, A., Appl. Catal., 2000, vol. 202, pp. 183–196. https://doi.org/10.1016/S0926-860X(00)00525-1
Stagg-Williams, S.M., Noronha, F.B., Fendley, G., and Resasco, D., J. Catal., 2000, vol. 194, no. 2, pp. 240–249. https://doi.org/10.1006/jcat.2000.2939
Maestri, M., Vlachos, D., Beretta, A., Groppi, G., and Tronconi, E., J. Catal., 2008, vol. 259, pp. 211–222. https://doi.org/10.1016/j.jcat.2008.08.008
Barbier, J., Appl. Catal., 1986, vol. 23, no. 2, pp. 225–243. https://doi.org/10.1016/S0166-9834(00)81294-4
Pant, B. and Stagg-Williams, S.M., Catal. Commun., 2004, vol. 5, pp. 305–309. https://doi.org/10.1016/j.catcom.2004.03.009
Cui, Y., Zhang, H., Xu, H., and Li, W., Appl. Catal., 2007, vol. 318, pp. 79–88. https://doi.org/10.1016/j.apcata.2006.10.044
Topalidis, A., Petrakis, D.E., Ladavos, A., and Loukatzikou, L., Catal. Today, 2007, vol. 127, nos. 1–4, pp. 238–245. https://doi.org/10.1016/j.cattod.2007.04.015
Erdöhelyi, A., Cserényi, J., Papp, E., and Solymosi, F., Appl. Catal. A: General, 1994, vol. 108, no. 2, pp. 205–219. https://doi.org/10.1016/0926-860X(94)85071-2
Richardson, J.T. and Paripatyadar, S.A., Appl. Catal., 1990, vol. 61, no. 1, pp. 293–309. https://doi.org/10.1016/S0166-9834(00)82152-1
Özkara-Aydınoğlu, S. and Aksoylu, A.E., Int. J. Hydrogen Energy, 2011, vol. 36, no. 4, pp. 2950–2959. https://doi.org/10.1016/j.ijhydene.2010.11.080
Özkara-Aydınoğlu, S. and Erhan Aksoylu, A., Chem. Eng. J., 2013, vols. 215–216, pp. 542–549. https://doi.org/10.1016/j.cej.2012.11.034
Quiroga, M.M. and Castro Luna, A.E., Ind. Eng. Chem. Res., 2007, vol. 46, pp. 5265–5270. https://doi.org/10.1021/ie061645w
Luo, J.Z., Yu, Z.L., Ng, C.F., and Au, C.T., J. Catal., 2000, vol. 194, no. 2, pp. 198–210. https://doi.org/10.1006/jcat.2000.2941
Mark, M.F., Maier, W.F., and Mark, F., Chem. Eng. Technol., 1997, vol. 20, no. 6, pp. 361–370. https://doi.org/10.1002/ceat.270200602
Guo, J., Lou, H., Zhao, H., Chai, D., and Zheng, X., Appl. Catal. A, 2004, vol. 273, pp. 75–82. https://doi.org/10.1016/j.apcata.2004.06.014
Souza, M.M.V., Aranda, D.A., and Schmal, M., J. Catal., 2001, vol. 204, no. 2, pp. 498–511. https://doi.org/10.1006/jcat.2001.3398
Foo, S.Y., Cheng, C.K., Nguyen, T.H., and Adesina, A.A., Ind. Eng. Chem. Res., 2010, vol. 49, no. 21, pp. 10450–10458. https://doi.org/10.1021/ie100460g
Kohn, M.P., Castaldi, M.J., and Farrauto, R.J., Appl. Catal. B: Environmental, 2010, vol. 94, nos. 1–2, pp. 125–133. https://doi.org/10.1016/j.apcatb.2009.10.029
Chettapongsaphan, C., Charojrochkul, S., Assabumrungrat, S., and Laosiripojana, N., Appl. Catal. A, 2010, vol. 386, pp. 194–200. https://doi.org/10.1016/j.apcata.2010.07.053
Koubaissy, B., Pietraszek, A., Roger, A.C., and Kiennemann, A., Catal. Today, 2010, vol. 157, nos. 1–4, pp. 436–439. https://doi.org/10.1016/j.cattod.2010.01.050
García-Diéguez, M., Pieta, I.S., Herrera, M.C., Larrubia, M.A., and Alemany, L.J., J. Catal., 2010, vol. 270, pp. 136–145. https://doi.org/10.1016/j.jcat.2009.12.010
Garcia-Dieguez, M., Pieta, I.S., Herrera, M.S., Larrubia, M.A., and Alemany, L.J., Catal. Today, 2011, vol. 172, pp. 136–142. https://doi.org/10.1016/j.cattod.2011.02.012
Wu, J.C.S. and Chou, H.C., Chem. Eng. J., 2009, vol. 148, nos. 2–3, pp. 539–545. https://doi.org/10.1016/j.cej.2009.01.011
Gallego, G.S., Batiot-Dupeyrat, C., Barrault, J., Florez, E., and Mondragón, F., Appl. Catal. A: General, 2008, vol. 334, nos. 1–2, pp. 251–258. https://doi.org/10.1016/j.apcata.2007.10.010
Tao, K., Zhang, Y., Terao, S., and Tsubaki, N., Catal. Today, 2010, vol. 153, pp. 150–155. https://doi.org/10.1016/j.cattod.2010.02.061
Bhavani, A.G., Kim, W.Y., Kim, J.Y., and Lee, J.S., Appl. Catal. A: General, 2013, vol. 450, pp. 3–72. https://doi.org/10.1016/j.apcata.2012.10.008
Ghelamallah, M. and Granger, P., Fuel, 2012, vol. 97, pp. 269–276. https://doi.org/10.1016/j.fuel.2012.02.068
Haynes, D.J., Campos, A., Berry, D.A., Shekhawat, D., Roy, A., and Spivey, J.J., Catal. Today, 2010, vol. 155, pp. 84–91. https://doi.org/10.1016/j.cattod.2009.03.025
Stagg-Williams, S.M., Soares, R., Romero, E., and Alvarez, W.E., Stud. Surf. Sci. Catal., 2000, vol. 130, pp. 3663–3668. https://doi.org/10.1016/S0167-2991(00)80592-3
Kharton, V. and Marques, F.M., Curr. Opin. Solid State Mater. Sci., 2002, vol. 6, no. 3, pp. 261–269. https://doi.org/10.1016/S1359-0286(02)00033-5
Soria, M.A., Mateos-Pedrero, C., Guerrero-Ruiz, A., and Rodríguez-Ramos, I., Int. J. Hydrogen Energy, 2011, vol. 36, no. 23, pp. 15212–15220. https://doi.org/10.1016/j.ijhydene.2011.08.117
McGuire, N.E., Sullivan, N.P., Deutschmann, O., Zhu, H., and Kee, R.J., Appl. Catal. A: General, 2011, vol. 394, nos. 1–2, pp. 257–265. https://doi.org/10.1016/j.apcata.2011.01.009
Yang, Z., Chem. Commun., 2014, vol. 50, pp. 13910–13913. https://doi.org/10.1039/C4CC06423B
Foo, S., Ind. Eng. Chem. Res., 2010, vol. 49, no. 21, pp. 10450–10458. https://doi.org/10.1021/ie100460g
Yamazaki, O., Chem. Lett., 1992, vol. 21, no. 10, pp. 1953–1954. https://doi.org/10.1246/cl.1992.1953
Wang, N., Int. J. Hydrogen Energy, 2012, vol. 37, pp. 19–30. https://doi.org/10.1016/j.ijhydene.2011.03.138
Yamazaki, O., Appl. Catal. A: General, 1996, vol. 136, pp. 49−56. https://doi.org/10.1016/0926-860X(95)00268-5
Chen, Y., Appl. Catal. A: General, 1997, vol. 165, nos. 1–2, pp. 335–347. https://doi.org/10.1016/S0926-860X(97)00216-0
Ruckenstein, R.E., Ind. Eng. Chem. Res., 1998, vol. 37, no. 5, pp. 1744–1747. https://doi.org/10.1021/ie9707883
Wang, S. and Lu, C.Q., Appl. Catal., 1998, vol. B19, no. 34, pp. 267–277. https://doi.org/10.1016/S0926-3373(98)00081-2
Chen, P., Zhang, H.B., Lin, G.D., and Tsai, K.R., Appl. Catal., 1998, vol. A166, no. 12, pp. 343–350. https://doi.org/10.1016/S0926-860X(97)00291-3
Erdöhelyi, A., Stud. Surf. Sci. Catal., 1997, vol. 107, pp. 525–530. https://doi.org/10.1016/S0167-2991(97)80385-0
O’Connor, A.M. and Ross, J.R.H., Abstracts of Papers, 5th European Workshop on Methane Activation, Linerik (Ireland), 1997, vol. 1, pp. 46–47.
Stagg, S., J. Catal., 1998, vol. 178, no. 1, pp. 137–145. https://doi.org/10.1006/jcat.1998.2146
Wang, S., Appl. Catal. A: General, 1995, vol. 133, no. 1, pp. 149–161. https://doi.org/10.1021/ef950227t
Dalai, A.K., Appl. Catal. A: General, 2008, vol. 339, pp. 121–129. https://doi.org/10.1016/j.apcata.2008.01.027
Carrara, C., Top. Catal., 2008, vol. 51, nos. 1–4, pp. 98–106. https://doi.org/10.1021/ie061621p
Dias, J., Catal. Today, 2003, vol. 85, pp. 59–68. https://doi.org/10.1016/S0920-5861(03)00194-9
Sengupta, S., J. CO2 Util., 2015, vol. 10, pp. 67–77. https://doi.org/10.1016/j.jcou.2015.04.003
Li, H., Chem. Eng. Sci., 2004, vol. 59, pp. 4861–4867. https://doi.org/10.1016/j.ces.2004.07.076
Nakagawa, Y., Chin. J. Catal., 2012, vol. 33, no. 4–6, pp. 583–594. https://doi.org/10.1016/S1872-2067(11)60359-8
Moradi, G., J. Nat. Gas. Sci. Eng., 2016, vol. 33, pp. 657–665. https://doi.org/10.1016/j.jngse.2016.06.004
Xu, L., ACS Catal., 2012, vol. 2, no. 7, pp. 1331–1342. https://doi.org/10.1021/cs3001072
Zhao, Z., RSC Adv., 2016, vol. 6, no. 55, pp. 49487–49496. https://doi.org/10.1039/C6RA09203A
Fan, M., Abdullah, A.Z., and Bhatia, S., ChemCatChem, 2009, vol. 1, pp. 192–208. https://doi.org/10.1002/cctc.200900025
Lapidus, A.L., Golubeva, I.A., and Zhagfarov, F.G., Gazokhimiya (Gas Chemistry), Moscow: Ross. Gos. Univ. Nefti i Gaza im. I.M. Gubkina, 2013.
Van der Osterkamp, P. and Wagner, E., Ross. Khim. Zh., 2000, vol. 44, pp. 34–35.
Teuner, S.C., Neumann, P., and Von Linde, F., Oil Gas Eur. Mag., 2001, vol. 27, no. 3, pp. 44–46.
Rostrup-Nielsen, J., Catal. Today, 2006, vol. 111, pp. 4–11. https://doi.org/10.1016/j.cattod.2005.10.002
Funding
The study was financially supported by the Ministry of Science and Higher Education of the Russian Federation; unique project identifier RFMEFI60719X0296.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
A.L. Maksimov is the Editor-in-Chief of Zhurnal Prikladnoi Khimii/Russian Journal of Applied Chemistry; the other authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Nedolivko, V.V., Zasypalov, G.O., Vutolkina, A.V. et al. Carbon Dioxide Reforming of Methane. Russ J Appl Chem 93, 765–787 (2020). https://doi.org/10.1134/S1070427220060014
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427220060014