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Study of Structural Changes in LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries by X-Ray Diffraction Analysis in the In Situ Mode

  • Applied Electrochemistry and Metal Corrosion Protection
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Abstract

Structural changes in a promising cathode material LiNi0.8Co0.1Mn0.1O2 for lithium-ion batteries were in situ studied by X-ray diffraction analysis in the course of electrochemical reactions. The Rietveld method and TOPAS 5 software package were used to examine changes in the unit cell parameters of LiNi0.8Co0.1Mn0.1O2 and the reasons for these changes. It was found that the unit cell volume increases by 2% relative to the discharged state (2.7 V) upon charging to 4.2 V.

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Authors and Affiliations

  1. Zheang Changxing CHN/RUS New Energy and Material Technology Research Institute, Zhejiang, Changxing County, China

    P. A. Novikov, A. E. Kim, K. A. Pushnitsa & Wang Quingsheng

  2. Peter the Great St. Petersburg Polytechnic University, St. Petersburg, 195251, Russia

    P. A. Novikov, A. E. Kim, Wang Quingsheng, M. Yu. Maksimov & A. A. Popovich

  3. St. Petersburg State Technological Institute (Technical University), St. Petersburg, 190013, Russia

    K. A. Pushnitsa

Authors
  1. P. A. Novikov
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  2. A. E. Kim
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  3. K. A. Pushnitsa
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  4. Wang Quingsheng
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  5. M. Yu. Maksimov
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  6. A. A. Popovich
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Corresponding authors

Correspondence to A. E. Kim or K. A. Pushnitsa.

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Conflict of Interest

The authors that there is no conflict of interest to be disclosed in the present communication.

Russian Text © The Author(s), 2019, published in Zhurnal Prikladnoi Khimii, 2019, Vol. 92, No. 7, pp. 920–926.

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Novikov, P.A., Kim, A.E., Pushnitsa, K.A. et al. Study of Structural Changes in LiNi0.8Co0.1Mn0.1O2 Cathode Material for Lithium-Ion Batteries by X-Ray Diffraction Analysis in the In Situ Mode. Russ J Appl Chem 92, 1013–1019 (2019). https://doi.org/10.1134/S1070427219070188

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  • DOI: https://doi.org/10.1134/S1070427219070188

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