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Conversion of Straight-Run Naphtha to C5−C6 Alkanes on Co(Ni)/HZSM–5/SO 2-4 —ZrO2 Composite Catalysts

  • Organic Synthesis and Industrial Organic Chemistry
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Abstract

The conversion of straight-run naphtha on composite catalytic systems containing HZSM-5 zeolite modified with 0.4 wt % Co or Ni and 15% SZ (10% SO 2-4 /ZrO2), performed at atmospheric pressure in the interval 140–200°C, was studied. At 140–200°C, the major products of straight-run naphtha conversion are branched C5−C6 alkanes. At T ≥ 180°C, the reaction products become enriched in gaseous alkanes. Analysis of the conversion products suggests that the process occurs via formation of a skeleton-isomerized intermediate, followed by its cleavage (disproportionation) at the β- or α-bond. The conversion is influenced by the conditions of the reaction and reduction of the composite catalytic system. On the Co-containing composite catalyst reduced at 380°C, the conversion of C8+ components of straight-run naphtha at 180°C, feed space velocity of 2.5 h−1, and H2/CH = 3 is 76.8%, and the content of C5−C6 alkanes consisting to 78% of isoparaffins reaches 61%.

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Correspondence to M. T. Mamedova.

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Abasov, S.I., Agayeva, S.B., Mamedova, M.T. et al. Conversion of Straight-Run Naphtha to C5−C6 Alkanes on Co(Ni)/HZSM–5/SO 2-4 —ZrO2 Composite Catalysts. Russ J Appl Chem 92, 228–234 (2019). https://doi.org/10.1134/S1070427219020095

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  • DOI: https://doi.org/10.1134/S1070427219020095

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