Abstract
UV spectroscopy and cyclic voltammetry were used to examine the thermochemical and electrochemical stabilities of liquid sulfolane-based electrolyte systems for lithium and lithium-ion batteries. It was found that solutions of lithium salts in sulfolane are stable in prolonged keeping at 100°C. The thermochemical stability of lithium salt solutions in sulfolane changes in the order LiBF4 > LiClO4 ≈ LiN(CF3SO2)2 > LiCF3SO3. It was shown that the electrochemical stability of lithium salt solutions in sulfolane is in the range from 5.5 to 5.9 V (relative to Li/Li+) and prolonged action of high temperatures (100°C) does not yield electrochemically active thermal destruction products.
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Original Russian Text © L.V. Sheina, E.V. Kuz’mina, E.V. Karaseva, A.G. Gallyamov, T.R. Prosochkina, V.S. Kolosnitsyn, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 9, pp. 1257–1264.
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Sheina, L.V., Kuz’mina, E.V., Karaseva, E.V. et al. Thermochemical and Electrochemical Stability of Electrolyte Systems based on Sulfolane. Russ J Appl Chem 91, 1427–1433 (2018). https://doi.org/10.1134/S1070427218090045
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DOI: https://doi.org/10.1134/S1070427218090045