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Formation, nature of activity, and hydrogenation catalysis by nickel bis(acetylacetonate)-lithium tetrahydroaluminate systems

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

A new approach to synthesis of nickel catalysts under the action of lithium tetrahydroaluminate was proposed which allows preparation of high-performance nanosized catalytic systems with well-reproducible properties. The major stages of formation and the nature of catalytically active species and inhibitors formed in the Ni(acac)2-LiAlH4 system were determined. The catalytic properties of the nickel nanoclusters were studied in relation to the nature and concentration of the proton-containing compounds. Factors responsible for the promoting action exhibited by these compounds were analyzed.

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Authors and Affiliations

  1. Irkutsk State University, Irkutsk, Russia

    L. B. Belykh, Yu. Yu. Titova, A. V. Rokhin & F. K. Shmidt

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  1. L. B. Belykh
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  2. Yu. Yu. Titova
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  3. A. V. Rokhin
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  4. F. K. Shmidt
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Original Russian Text © L.B. Belykh, Yu.Yu. Titova, A.V. Rokhin, F.K. Shmidt, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 11, pp. 1778–1786.

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Belykh, L.B., Titova, Y.Y., Rokhin, A.V. et al. Formation, nature of activity, and hydrogenation catalysis by nickel bis(acetylacetonate)-lithium tetrahydroaluminate systems. Russ J Appl Chem 83, 1911–1918 (2010). https://doi.org/10.1134/S1070427210110030

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  • DOI: https://doi.org/10.1134/S1070427210110030

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