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Ytterbium Ate Complexes with 1,2-Bisimine Ligand: Paramagnetic NMR

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Abstract

The reaction of [(dpp-bian)Yb(DME)2] with one equivalent of dpp-bian and one equivalent of potassium or sodium gave the ate complexes [(dpp-bian)2Yb][K(DME)4] and [(dpp-bian)2Yb][Na(THF)6]. The reaction of [(dpp-bian)YbI(DME)]2 with potassium cyclopentadienide (CpK) led to the complex [{(dpp-bian)CpYb(μ-Cp)· K(Et2O)2}2(μ-Cp)2Yb(THF)2]. In all three compounds, the redox-active dpp-bian exhibits a dianionic state. Yb3+ cations in the prepared compounds determine their paramagnetism. Despite this, resolved 1H and 13C NMR spectra were obtained for [(dpp-bian)2Yb][K(DME)4] and [(dpp-bian)2Yb][Na(THF)6] in THF-d8, which made it possible to assign observed signals. The new compounds were characterized by IR and NMR spectroscopy and elemental analysis (C, H, N). The molecular structure of the prepared complexes was determined by X-ray diffraction

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Funding

This work was supported by the Russian Science Foundation (grant no. 21-73-20153). The work was carried out using the equipment of the Center for Collective Use “Analytical Center of the IOMC RAS” with the financial support of the grant “Ensuring the development of the material and technical infrastructure of the centers for collective use of scientific equipment” (unique identifier RF-2296.61321X0017, agreement no. 075-15-2021-670).

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  1. G.A. Razuvaev Institute of Organometallic Chemistry of the Russian Academy of Sciences, 603950, Nizhny Novgorod, Russia

    V. A. Dodonov, D. A. Razborov, E. V. Baranov & I. L. Fedushkin

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  1. V. A. Dodonov
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Dodonov, V.A., Razborov, D.A., Baranov, E.V. et al. Ytterbium Ate Complexes with 1,2-Bisimine Ligand: Paramagnetic NMR. Russ J Gen Chem 93 (Suppl 3), S794–S804 (2023). https://doi.org/10.1134/S1070363223160181

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