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Synthesis of (Thio)semicarbazones Combining Adamantane and 3,7-Dimethyloctyl Fragments

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Abstract

A series of new (thio)semicarbazones containing adamantane and 3,7-dimethyloctyl fragments was synthesized. The configuration of imine bond was proposed based on the characteristic signals of 1Н and 13С NMR spectra simulated by quantum-chemical calculations.

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ACKNOWLEDGMENTS

The authors thank the Information and Computing Center of the Novosibirsk State University for the provided computing resources, and also express gratitude to the Chemical Research Center for Collective Use of the Siberian Branch of the Russian Academy of Sciences for carrying out spectral and analytical measurements.

Funding

The work was financially supported by the Russian Science Foundation (grant no. 22-73-00340).

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Authors and Affiliations

  1. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090, Novosibirsk, Russia

    E. S. Mozhaitsev, E. V. Suslov, K. Yu. Ponomarev, K. P. Volcho & N. F. Salakhutdinov

  2. Tomsk State University, 634050, Tomsk, Russia

    A. V. Marakulin

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  1. E. S. Mozhaitsev
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  2. A. V. Marakulin
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  3. E. V. Suslov
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  5. K. P. Volcho
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  6. N. F. Salakhutdinov
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Correspondence to E. S. Mozhaitsev.

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Mozhaitsev, E.S., Marakulin, A.V., Suslov, E.V. et al. Synthesis of (Thio)semicarbazones Combining Adamantane and 3,7-Dimethyloctyl Fragments. Russ J Gen Chem 93 (Suppl 2), S450–S455 (2023). https://doi.org/10.1134/S1070363223150057

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