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Palladium Complex of Camphor-Substituted Tetrapyrazinoporphyrazine as a Stationary Phase of Gas Chromatography

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Abstract

Surface modification of the diatomite adsorbent Hezasorb AW-HMDS by tetra(1,7,7-trimethylbicyclo[2.2.1]heptane[2,3-b]pyrazino)porphyrazine Pd(II) was conducted. Using gas chromatography, adsorption of vapors of several organic compounds was studied on the surface of modified adsorbents. Electron donating isomers of methylpyridine and dimethylpyridine, isomers of non-polar xylenes, alcohols and other hydrocarbons capable of various types of intermolecular interactions with metal pyrazinoporphyrazine were selected as sorbates. Specific retention volumes of sorbates, heights equivalent to theoretical plates, the number of theoretical plates to characterizt chromatograms were calculated. Influence of temperature and sorbate chemical nature on thermodynamic characteristics of sorption were discussed. Separation factors of close-boiling point aromatic and heteroaromatic compounds were calculated. It was experimentally proven that tetra(1,7,7-trimethylbicyclo[2.2.1]heptane[2,3-b]pyrazino)porphyrazine Pd(II) shows high selectivity to close-boiling point compounds of various nature and is good in their separation.

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Authors and Affiliations

  1. Federal State Budget Educational Establishment of Higher Education “Ivanovo Fire Rescue Academy of State Firefighting Service of Ministry of Russian Federation for Civil Defense, Emergencies and Elimination of Consequences of Natural Disasters”, 153040, Ivanovo, Russia

    G. V. Kuvshinov, A. V. Surovegin, M. O. Bakanov & A. V. Maslov

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  1. G. V. Kuvshinov
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  2. A. V. Surovegin
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  3. M. O. Bakanov
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  4. A. V. Maslov
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Correspondence to A. V. Surovegin.

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Kuvshinov, G.V., Surovegin, A.V., Bakanov, M.O. et al. Palladium Complex of Camphor-Substituted Tetrapyrazinoporphyrazine as a Stationary Phase of Gas Chromatography. Russ J Gen Chem 91, 2606–2612 (2021). https://doi.org/10.1134/S1070363221120318

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