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Synthesis and Spectral-Luminescent Properties of Fluorescent Dyads Based on Tetraarylimidazole and Azomethines of Various Nature

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Abstract

Synthesis and structure of two novel dyads including two fluorophores - 1,2,4,5-tetraarylimidazole and azomethine fragments of different nature, have been studied targeting compounds with tunable luminescence. The presence of multiple fluorescence in both dyads has been established, and switching in one of the compounds is controlled by the excitation wavelength.

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REFERENCES

  1. Padalkar, V.S. and Seki, S., Chem. Soc. Rev., 2016, vol. 45, p. 169. https://doi.org/10.1039/C5CS00543D

    Article  CAS  PubMed  Google Scholar 

  2. Park, S., Kwon, J.E., Kim, S.H., Seo, J., Chung, K., Par, S.Y., Jang, D.J., Medina, B.W., Giecher, J., and Park, S.Y., J. Am. Chem. Soc., 2009, vol. 131, p. 14043. https://doi.org/10.1021/ja902533f

  3. Heyer, E., Nassue, J., and Ulrich, G., Dyes Pigments, 2017, vol. 143, p. 18. https://doi.org/10.1016/j.dyepig.2017.04.020

    Article  CAS  Google Scholar 

  4. Tasaki, S., Momotake, A., Kanna, Y., Sato, T., Nishimura, Y., Arai, T., Photochem. Photobiol. Sci., 2015, vol. 14, p. 1864. https://doi.org/10.1039/C5PP00088B

  5. Ma, H., Chen, B.Q., Sassa, T., Dalton, L.R., and Jen, A.K.Y., J. Am. Chem. Soc., 2001, vol. 123, p. 986. https://doi.org/10.1021/ja003407c

  6. Levin, P.P., Liubimov, A.V., Shashkov, A.S.,. Mardaleishvili, I.R, Venidiktova, O.V., Shienok, A.I., Koltsova, L.S., Astafiev, A.A., Barachevsky, V.A., and Zaichenko, N.L., Dyes Pigments, 2020, vol. 183, p. 108716. https://doi.org/10.1016/j.dyepig.2020.108716

  7. Mardaleishvili, I.R., Luybimova, G.V., Luybimov, A.V., Kol’tsova, L.S., Shienok, A.I., Levin, P.P., Tatikolov, A.S., and Zaichenko, N.L., High Energy Chem., 2020, vol. 54, p. 15. https://doi.org/10.1134/S0018143920010099

  8. Shienok, A.I., Kol’tsova, L.S., Zaichenko, N.L., and Marevtsev, V.S., Russ Chem. Bull., 2002, vol. 51, p. 2050. https://doi.org/10.1023/A:1021607825803

    Article  CAS  Google Scholar 

  9. Fabian, W.M.F., Antonov, L., Nedeltcheva, D., Kamounah, F.S., and Taylor, P.J.J., Phys. Chem. A, 2004, vol. 108, p. 7603. https://doi.org/10.1021/jp048035z

  10. Ziolek, M., Kubicki, J., Maciejewski, A., Naskrecki, R., and Grabowska, A., J. Chem. Phys., 2006, vol. 124, p. 124518. https://doi.org/10.1063/1.2179800

    Article  CAS  PubMed  Google Scholar 

  11. Fita, P., Lusina, E.. Radzewicz, Cz., and Grabowska, A., J. Chem. Phys., 2006, vol. 125, p. 18450. https://doi.org/10.1063/1.2371058

  12. Ziolek, M., Kubicki J., Maciejewski A., Naskrecki, R., Grabowska, A., J. Chem. Phys., 2006, vol. 124, p. 124518. https://doi.org/10.1063/1.2179800

  13. Levin, P.P., Zaichenko, N.L., Shienok, A.I., Koltsova, L.S., Mardaleishvili, I.R., and Tatikolov, A.S., Russ. Chem. Bull. Int. Ed., 2012, vol. 61, p. 532. https://doi.org/10.1007/s11172-012-0078-6

  14. Levin, P.P., Tatikolov, A.S., Zaichenko, N.L., Shienok, A.I., Koltsova, L.S., Mardaleishvili, I.R., and Berlin, A.A., Photochem. Photobiol. Sci., 2016, vol. 15, p. 382. https://doi.org/10.1039/c5pp00314h

  15. Krasovitskii, V.M. and Bolotin, B.M., Organicheskie luiminofory (Organic Luminophores), Moscow: Khimiya, 1984.

  16. Vargas, V., J. Phys. Chem. A, 2024, vol. 108, p. 281. https://doi.org/10.1021/jp035461

  17. Bren’, V.A., Usacheva, V.I., and Minkin, V.I., Chem. Heterocycl. Compd., 1972, vol. 8, p. 836. https://doi.org/10.1007/BF00475214

    Article  Google Scholar 

  18. Bren’, Zh.V., Usacheva, V.I., Palui, G.D., Bren’, V.A., and Minkin, V.I., Chem. Heterocycl. Compd., 1977, vol. 13, p. 498. https://doi.org/10.1007/BF00473194

    Article  Google Scholar 

  19. Rybalkin,V.P., Shepelenko, E.N., Popova, L.L., Duonosov, A.D., and Bren’, V.A., Russ. Org. Chem., 1996, vol. 32, no. 1, p. 90.

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Funding

This work was supported by Russian Ministry of Education and Science (State tasks of N.N. Semenov Federal Research Centre for Chemical Physics, topic 0082-2019-0003).

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Correspondence to N. L. Zaichenko.

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Shienok, A.I., Krutius, O.N., Mardaleishvili, I.R. et al. Synthesis and Spectral-Luminescent Properties of Fluorescent Dyads Based on Tetraarylimidazole and Azomethines of Various Nature. Russ J Gen Chem 91, 2101–2109 (2021). https://doi.org/10.1134/S1070363221100285

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  • DOI: https://doi.org/10.1134/S1070363221100285

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