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Syntheses, Structure, and Properties of a Novel Cobalt Metal-Organic Framework

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Abstract

A novel cobalt metal-organic framework {[Co2(ltzdc)2(bpe)]·bpe·4H2O}n, MOF (1), has been synthesized by hydrolysis of letrozole (H2ltzdc) and 1,2-di(4-pyridyl)ethylene (bpe) coligand under hydrothermal conditions. Structure of MOF (1) has been determined by single crystal X-ray diffraction. The central Co(II) adopts a distorted tetrahedral coordination configuration and is extended by ltzdc and bpe ligands to form a three-dimensional (3D) pillar-layered framework existing in a 3-fold interpenetrated mode. The powder X-ray diffraction and thermogravimetric analysis demonstrate that the MOF (1) upon heating transforms into MOF (2), that has a retentively porous structure, upon removal of the guest molecules by heating at 300°C in the air. The preliminary antibacterial activity tests indicate MOF (2) as an antibacterial compound against Bacillus subtilis.

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Fig. 1.

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Funding

This work was supported by the Project of Science and Technology in Henan Province (no. 172102310441) and the National Natural Science Foundation of China (no. 21571093)

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Authors and Affiliations

  1. School of Food and Drug, Luoyang Normal University, Luoyang, 471934, Henan, China

    H. X. Kang

  2. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, Luoyang, 471934, Henan, China

    Y. Q. Fu, L. Y. Xin & G. Z. Liu

  3. College of Food and Bioengineering, Henan University of Science and Technology, 471000, Luoyang, China

    M. Jiu & L. J. Wang

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  1. H. X. Kang
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  2. Y. Q. Fu
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  4. M. Jiu
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  6. G. Z. Liu
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Correspondence to G. Z. Liu.

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Kang, H.X., Fu, Y.Q., Xin, L.Y. et al. Syntheses, Structure, and Properties of a Novel Cobalt Metal-Organic Framework. Russ J Gen Chem 90, 2365–2370 (2020). https://doi.org/10.1134/S107036322012021X

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