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New Tetrazole Tripodal Ligand Based on Triphenylphosphine Oxide

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Abstract

A new tetrazole tripodal ligand, tris[2-(tetrazol-5-ylmethoxy)phenyl]phosphine oxide, has been obtained. Its structure in crystal and solutions has been elucidated by X-ray diffraction analysis as well as IR, Raman, and multinuclear (1H, 13C, 31P) NMR spectroscopy. Coordination properties of the polydentate ligand have been studied as exemplified by the complexation with lanthanum(III).

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Funding

This study was financially supported by the Russian Foundation for Basic Research (project 17-03-00800). X-ray diffraction experiments as well as NMR, IR, and Raman studies have been performed with support from the Ministry of Science and Higher Education of the Russian Federation using the equipment of the Center for Study of Molecular Structure, Institute of Organoelement Compounds (Russian Academy of Sciences).

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Authors and Affiliations

  1. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 119991, Russia

    O. V. Bykhovskaya, A. G. Matveeva, M. P. Pasechnik, A. V. Vologzhanina, S. V. Matveev, I. Yu. Kudryavtsev, T. V. Baulina & V. K. Brel

Authors
  1. O. V. Bykhovskaya
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  2. A. G. Matveeva
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  3. M. P. Pasechnik
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  4. A. V. Vologzhanina
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  5. S. V. Matveev
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  6. I. Yu. Kudryavtsev
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  7. T. V. Baulina
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  8. V. K. Brel
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Corresponding author

Correspondence to A. G. Matveeva.

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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1885–1894.

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Bykhovskaya, O.V., Matveeva, A.G., Pasechnik, M.P. et al. New Tetrazole Tripodal Ligand Based on Triphenylphosphine Oxide. Russ J Gen Chem 89, 2400–2407 (2019). https://doi.org/10.1134/S1070363219120120

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  • DOI: https://doi.org/10.1134/S1070363219120120

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