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Kinetic Stability of Tetra(1,2,5-selenodiazolo)porphyrazine in the Nitrogen-Containing Base-Dimethyl Sulfoxide System

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Abstract

The behavior of tetra(1,2,5-selenodiazolo)porphyrazine in DMSO and in the DMSO-base (pyridine, 2-methyl-pyridine, morpholine, and piperidine) systems has been studied. It has been shown that the π-chromophore system of the macrocycle is decomposed with time in strongly basic media. The proton-transfer complex H2PA(SeN2)4·2DMSO formed in DMSO has been less kinetically stable in the presence of morpholine (piperidine) than the H2PA(SN2)4·2DMSO complex.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, prosp. Sheremetevskii 7, Ivanovo, 153000, Russia

    O. A. Petrov, Z. A. Teletskii & A. O. Belyaeva

  2. Krestov Institute of Solution Chemistry of the Russian Academy of Sciences, Ivanovo, Russia

    A. N. Kiselev

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  1. O. A. Petrov
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  2. A. N. Kiselev
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  3. Z. A. Teletskii
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  4. A. O. Belyaeva
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Correspondence to O. A. Petrov.

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Petrov, O.A., Kiselev, A.N., Teletskii, Z.A. et al. Kinetic Stability of Tetra(1,2,5-selenodiazolo)porphyrazine in the Nitrogen-Containing Base-Dimethyl Sulfoxide System. Russ J Gen Chem 89, 429–433 (2019). https://doi.org/10.1134/S1070363219030101

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  • DOI: https://doi.org/10.1134/S1070363219030101

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