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New Possibilities of the Kabachnik–Fields and Pudovik Reactions in the Phthalocyanine-Catalyzed Syntheses of α-Aminophosphonic and α-Aminophosphinic Acid Derivatives

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Abstract

The results of systematic studies demonstrated wide possibilities of the three-component Kabachnik–Fields and two-component Pudovik reactions catalyzed by metal phthalocyanines in the synthesis of structurally diverse α-aminophosphonates. Extension of this catalytic method to the synthesis α-aminophosphinates gave rise to a series of α-amino- and α-hydrazinophosphinates based on biogenic amino acids. A number of α-hydrazinophosphonates showed a good antioxidant activity.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    M. V. Shuvalov, S. Yu. Maklakova & T. A. Podrugina

  2. Institute of Physiologically Active Compounds, Russian Academy of Sciences, Severnyi proezd 1, Chernogolovka, Moscow oblast, 142432, Russia

    E. V. Rudakova, N. V. Kovaleva, G. F. Makhaeva & T. A. Podrugina

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  1. M. V. Shuvalov
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  2. S. Yu. Maklakova
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Correspondence to T. A. Podrugina.

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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth

Original Russian Text © M.V. Shuvalov, S.Yu. Maklakova, E.V. Rudakova, N.V. Kovaleva, G.F. Makhaeva, T.A. Podrugina, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1410–1425.

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Shuvalov, M.V., Maklakova, S.Y., Rudakova, E.V. et al. New Possibilities of the Kabachnik–Fields and Pudovik Reactions in the Phthalocyanine-Catalyzed Syntheses of α-Aminophosphonic and α-Aminophosphinic Acid Derivatives. Russ J Gen Chem 88, 1761–1775 (2018). https://doi.org/10.1134/S1070363218090013

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