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Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes

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Abstract

Dehydrocondensation reactions of silicon hydrides catalyzed by the rhodium(III) complex [RhCl3(Me2SO)3] in the absence of the second substrate were studied. It was found that the complex [RhCl3(Me2SO)3] catalyzed the dehydrocondensation reaction with the formation of compounds containing siloxane bonds. Analysis of NMR spectra has shown that the reaction of [RhCl3(Me2SO)3] with silicon hydride includes sequential desoxygenation of sulfoxide ligands to sulfide ligands with the complex [RhCl3(Me2S)3] formation.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology (Technical University), Moskovskii pr. 26, St. Petersburg, 190013, Russia

    A. A. Eliseeva, E. G. Prudnikova & N. K. Skvortsov

  2. St. Petersburg State University, St. Petersburg, Russia

    T. L. Panikorovskii

Authors
  1. A. A. Eliseeva
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  2. E. G. Prudnikova
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  3. T. L. Panikorovskii
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  4. N. K. Skvortsov
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Correspondence to A. A. Eliseeva.

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Original Russian Text © A.A. Eliseeva, E.G. Prudnikova, T.L. Panikorovskii, N.K. Skvortsov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 8, pp. 1398–1400.

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Eliseeva, A.A., Prudnikova, E.G., Panikorovskii, T.L. et al. Reactions of silicon hydrides catalyzed by rhodium(III) sulfoxide complexes. Russ J Gen Chem 87, 1884–1886 (2017). https://doi.org/10.1134/S1070363217080400

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  • DOI: https://doi.org/10.1134/S1070363217080400

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