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Alkylation of CH acids with haloidalkyl-1,3-dioxolanes

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Abstract

Alkylation of diethyl malonate and Meldrum acid with haloalkyl-1,3-dioxolanes has afforded the substituted malonates; their decarboxylation has led to the formation of esters containing a cycloacetal fragment. Reactions of the substituted malonates with urea have yielded the corresponding substituted barbiturates. Monodecarboxylation of the obtained malonates has led to the formation of 1,3-dioxolane-carboxylates.

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Authors and Affiliations

  1. Ufa State Petroleum Technological University, ul. Kosmonavtov 1, Ufa, 450062, Russia

    G. Z. Raskil’dina, Yu. G. Borisova, L. V. Spirikhin & S. S. Zlotsky

Authors
  1. G. Z. Raskil’dina
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  2. Yu. G. Borisova
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  3. L. V. Spirikhin
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  4. S. S. Zlotsky
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Corresponding author

Correspondence to G. Z. Raskil’dina.

Additional information

Original Russian Text © G.Z. Raskil’dina, Yu.G. Borisova, L.V. Spirikhin, S.S. Zlotsky, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 5, pp. 872–875.

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Raskil’dina, G.Z., Borisova, Y.G., Spirikhin, L.V. et al. Alkylation of CH acids with haloidalkyl-1,3-dioxolanes. Russ J Gen Chem 87, 1097–1100 (2017). https://doi.org/10.1134/S1070363217050358

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  • DOI: https://doi.org/10.1134/S1070363217050358

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