Abstract
The Aurivillius phases Bi7Ti4NbO21, CaBi8Ti7O27, and SrBi8Ti7O27 were synthesized by solid-phase reactions. The results of high-temperature X-ray diffraction and thermal analyses of certain Aurivillius phases are presented. Principal regularities of thermal expansion of the synthesized compounds are established. A correlation between the Curie temperature and the structure of the compounds was found.
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Original Russian Text © A.V. Knyazev, O.V. Krasheninnikov, E.V. Syrov, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 2, pp. 194–201.
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Knyazev, A.V., Krasheninnikov, O.V. & Syrov, E.V. Phase transitions in mixed-layer Aurivillius phases. Russ J Gen Chem 87, 175–182 (2017). https://doi.org/10.1134/S1070363217020049
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DOI: https://doi.org/10.1134/S1070363217020049