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P/RS intergrowth type phases in the Ln2O3–MO–Al2O3 systems

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Abstract

Regularities of formation of complex aluminates with structure of P/RS intergrowth type phases in the Ln2O3–MO–Al2O3 systems (Ln = rare-earth element, M = Mg, Ca, Sr, Ba) have been considered. Systematization of the data on formation of complex compounds coexisting with one-layer phases in the Ln2O3–MO–Al2O3 systems and analysis of geometry criteria of LnMAlO4 stability is a promising approach to prediction of novel compounds with structure of Ruddlesden–Popper phase.

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  1. Ioffe Physico-Technical Institute, Russian Academy of Sciences, ul. Politekhnicheskaya 26, St. Petersburg, 194021, Russia

    E. A. Tugova

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Original Russian Text © E.A. Tugova, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 11, pp. 1766–1773.

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Tugova, E.A. P/RS intergrowth type phases in the Ln2O3–MO–Al2O3 systems. Russ J Gen Chem 86, 2410–2417 (2016). https://doi.org/10.1134/S1070363216110025

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  • DOI: https://doi.org/10.1134/S1070363216110025

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