Abstract
Hydrogenation of terminal β-acetylene alcohols with lithium aluminum hydride in THF has afforded homoallylic alcohols. Decomposition of the intermediate organoaluminum complex with deuterated water, iodine, or pyridinium dibromide has evidenced about the non-regioselective hydride attack at the triple bond.
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Original Russian Text © O.A. Garibyan, G.M. Makaryan, M.R. Ogannisyan, Zh.A. Chobanyan, 2016, published in Zhurnal Obshchei Khimii, 2016, Vol. 86, No. 2, pp. 239–244.
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Garibyan, O.A., Makaryan, G.M., Ogannisyan, M.R. et al. Hydroalumination of terminal β-acetylene alcohols with lithium aluminum hydride. Russ J Gen Chem 86, 267–272 (2016). https://doi.org/10.1134/S1070363216020109
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DOI: https://doi.org/10.1134/S1070363216020109