Skip to main content
SpringerLink
Log in

Solvent effects on the rate of thermolysis of lauroyl peroxide

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Thermolysis of lauroyl peroxide in various organic solvents was studied. It was shown that the primary homolytic dissociation of the peroxide group is accompanied by secondary reactions of chain-induced decomposition. The reaction medium affects the rate of both the primary homolytic dissociation and secondary induced decomposition processes. Correlation equations between the rate constants of the reactions in study and the physicochemical parameters of the solvents were proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reichardt, C., Solvent and Solvent Effects in Organic Chemistry, Weinheim: Chemie, 1988, 2 ed.

    Google Scholar 

  2. Antonovskii, V.L. and Khursan, S.I., Russ. Chem. Rev., 2003, vol. 72. no. 11, p. 939. DOI: 10.1070./RC 2003v072n11ABEH000749.

    Article  CAS  Google Scholar 

  3. Antonovskii, V.L. and Khursan, S.L., Fizicheskaya khimiya organicheskikh peroksidov (Physical Chemistry of Organic Peroxides), Moscow: Akademkniga, 2003.

    Google Scholar 

  4. Makitra, R.G., Polyuzin I.P., Golovata I.P., Russ. J. Gen. Chem., 2005, vol. 75. no. 2, p. 172. DOI: 10.1007/ s11176-005-0193-2.

    Article  CAS  Google Scholar 

  5. Midyana, G.G., Makitra, R.G., and Palchikova, E.Ya., Russ. J. Org. Chem., 2004, vol. 40. no. 10, p. 1407. DOI: 10. 1007/s111789-005-0032-2.

    Article  CAS  Google Scholar 

  6. Ivanchev, S.S., Radikal’naya polimerizatsiya (Radical Polymerization), Leningrad: Khimiya, 1985.

    Google Scholar 

  7. Antonovskii, V.L., Organicheskie perekisnye initsiatory (Organic Peroxide Initiators), Moscow: Khimiya, 1972.

    Google Scholar 

  8. Gavryliv, E.M., Makitra, R.G., and Pirig, Ya.N., Reakts. Sposobn. Org. Soedin., 1987, vol. 24, no. 1, p. 5.

    CAS  Google Scholar 

  9. Yatchishin, Y.Y., Pirig, Ya.N., and Makitra, R.G., Reakts. Sposobn. Org. Soedin., 1987, vol. 24, no. 3, p. 336.

    Google Scholar 

  10. Makitra, R.G. and Pirig, Ya.N., Zh. Org. Khim., 1996., vol. 32, no. 10, p. 1468.

    CAS  Google Scholar 

  11. Makitra, R.G., Pirig, Ya.N., and Yatchishin, Y.Y., Zh. Org. Khim., 1999, vol. 35, no. 7, p. 1073.

    Google Scholar 

  12. Makitra, R.G., Turovsky, A.A., and Zaikov, E.E., Correlation Analysis in Chemistry of Solution, Utrecht: VSP, 2004.

    Google Scholar 

  13. Koppel, I.A. and Palm, V.A., Advances in Linear Free Energy Relationships, London: Plenum, 1972, p. 203.

    Book  Google Scholar 

  14. Reichardt, C., Solvent and Solvent Effects in Organic Chemistry, Weinheim: Wiley–VCH, 2003, 3 ed.

    Google Scholar 

  15. Abboud, J.L.M. and Notario, R., Pure Appl. Chem., 1999, vol. 71, no. 4, p. 645. DOI: 10.1351/ pac199971040645.

    Article  CAS  Google Scholar 

  16. Makitra, R.G., Pirig, Ya.N., and Krivelyuk, R.V., Available from VINITI, 1986, Moscow, no. 628-V86.

    Google Scholar 

  17. Ventosa, N., Ruiz-Molina, D., Sedó Concepció Rovira, J., Tomas, X., André, J.-J., Bieber, A., and Veciana, J., Quant. Struct.-Act. Relat., 1985, vol. 4, no. 1, p. 29.

    Article  Google Scholar 

  18. Antonovskii, V.L. and Buzulanova, M.M., Analiticheskaya khimiya organicheskikh peroksidnykh soedinenii (Analytical Chemistry of Organic Peroxide Compounds), Moscow: Khimiya, 1978.

    Google Scholar 

  19. Organic Solvents, Weissberger, A., Proskauer,E.S., Riddick, J.A., and Toops, E.E., New York: Wiley, 1955.

  20. Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.

    Google Scholar 

  21. Dutka, V.S., Koval’skii, Ya.P., and Pankevich, R.V., Ukr. Khim. Zh., 1988, vol. 54, no. 4, p. 429.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Franko Lviv National University, Lviv, Ukraine

    V. S. Dutka & Yu. V. Dutka

  2. Litvinenko Institute of Physical Organic Chemistry and Coal Chemistry, National Academy of Sciences of Ukraine, ul. Nauchnaya 3a, Lviv, 79060, Ukraine

    G. G. Midyana

  3. Institute of Geology and Geochemistry of Fossil Fuels, National Academy of Sciences of Ukraine, Lviv, Ukraine

    E. Ya. Pal’chikova

Authors
  1. V. S. Dutka
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. G. G. Midyana
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. V. Dutka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Ya. Pal’chikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. S. Dutka.

Additional information

Original Russian Text © V.S. Dutka, G.G. Midyana, Yu.V. Dutka, E.Ya. Pal’chikova, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 12, pp. 1971–1977.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dutka, V.S., Midyana, G.G., Dutka, Y.V. et al. Solvent effects on the rate of thermolysis of lauroyl peroxide. Russ J Gen Chem 85, 2703–2709 (2015). https://doi.org/10.1134/S1070363215120063

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363215120063

Keywords

Search

Navigation