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Synthesis and spatial structure of P+–O(N)–C bipolar ions based of tris(diethylamino)phosphine and some 1,3-diketones

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Abstract

Reactions of tris(diethylamino)phosphine with indanetrione, 2-diazoindane-1,3-dione, 2-diazodimedone, and pyrimidine-2,4,5,6(1H,3H)-tetraone (alloxan) afforded crystalline adducts of bipolar type, whose structure was established by X-ray diffraction analysis.

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Correspondence to A. V. Bogdanov.

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Original Russian Text © A.V. Bogdanov, L.I. Musin, D.B. Krivolapov, A.B. Dobrynin, I.A. Litvinov, V.F. Mironov, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 9, pp. 1459–1464.

To the 85th Anniversary of birthday of late Yu.G. Gololobov

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Bogdanov, A.V., Musin, L.I., Krivolapov, D.B. et al. Synthesis and spatial structure of P+–O(N)–C bipolar ions based of tris(diethylamino)phosphine and some 1,3-diketones. Russ J Gen Chem 85, 2042–2047 (2015). https://doi.org/10.1134/S1070363215090054

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  • DOI: https://doi.org/10.1134/S1070363215090054

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