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Preparation and study of concentrated hydrosols of copper nanoparticles using of weak reducing agents

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Abstract

We propose a facile and environmentally friendly method to prepare concentrated copper nanoparticles dispersion via reduction of aqueous copper(II) sulfate solution with ascorbic acid or glucose in the presence of gelatin as stabilizer. The so synthesized hydrosols have been examined using a set of physicochemical methods (ex situ and in situ) in order to determine the nanoparticles features.

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References

  1. Chatterjee, A.K., Sarkar, R.K., Chattopadhyay, A.P., Aich, P., Chakraborty, R., and Basu, T., Nanotechnology, 2012, Vol. 23, No. 8, p. 085103. DOI: 10.1088/0957-4484/23/8/085103.

    Article  Google Scholar 

  2. Bi, Y. and Lu, G., Int. J. Hydrogen Energy, 2008, Vol. 33, No. 9, p. 2225. DOI: 10.1016/j.ijhydene.2008.02.064.

    Article  CAS  Google Scholar 

  3. Ding, R., Jiang, J., Wu, F., Gong, M., Zhu, J., and Huang, X., Nanotechnology, 2011, Vol. 22, No. 37, p. 330. DOI: 10.1088/0957-4484/22/37/375303.

    Google Scholar 

  4. Lin, J-H. and Guliants, V.V., Chem. Cat. Chem., 2011, Vol. 3, No. 9, p. 1426. DOI:10.1002/cctc.201100092.

    CAS  Google Scholar 

  5. Pomogailo, A.D., Rozenberg, A.S., and Uflyand, A.S., Nanochastitsy metallov v polimerakh (Metal Nanoparticles in Polymers), Moscow: Khimiya, 2000.

    Google Scholar 

  6. Rathmell, A.R., Bergin, S.M., Hua, Y.-L., Li, Z.-Y., and Wiley, B.J., Adv. Mater., 2010, Vol. 22, No. 32, p. 3558. DOI: 10.1002/adma.201000775.

    Article  CAS  Google Scholar 

  7. Yonezawa, T., Nishida, N., and Hyono, A., Chem. Lett., 2010, Vol. 39, No. 6, p. 548. DOI: 10.1246/cl.2010.548.

    Article  CAS  Google Scholar 

  8. Mallick, S., Sharma, S., Banerjee, M., Ghosh, S.S., Chattopadhyay, A., and Paul, A., ACS Appl. Mater. Interfaces, 2012, Vol. 4, No. 3, p. 1313. DOI: 10.1021/am201586w.

    Article  CAS  Google Scholar 

  9. Deng, D., Cheng, Y., Jin, Y., Qi, T., and Xiao, F., J. Mater. Chem., 2012, Vol. 22, No. 45, p. 23989. DOI: 10.1039/C2JM35041F.

    Article  CAS  Google Scholar 

  10. Gaponenko, S.V., Optika nanostruktur (The Optics of Nanostructures), St. Petersburg: Nedra, 2005.

    Google Scholar 

  11. Gubin, S.P. and Kataeva, N.A., Russ. J. Coord. Chem., 2006, Vol. 32, No. 12, p. 849. DOI: 10.1134/S1070328406120013.

    Article  CAS  Google Scholar 

  12. Shnaidman, L.O., Proizvodstvo vitaminov (Production of Vitamins), Moscow: Nauka, 1973.

    Google Scholar 

  13. Kang, J.S., Kim, H.S., Ryu, J., Thomas, H., Jang, H.S., and Joung, J.W., J. Mater. Sci.: Mater. Electron., 2010, Vol. 21, No. 11, p. 1213. DOI: 10.1007/s10854-009-0049-3.

    CAS  Google Scholar 

  14. Kim, D.-K., Yoo, S.M., Park, T.J., Yoshikawa, H., Tamiya, E., Park, J.Y., and Lee, S.Y., Anal. Chem., 2011, Vol. 83, No. 16, p. 6215. DOI: 10.1021/ac2007762.

    Article  CAS  Google Scholar 

  15. Chen, Z.-Z., Shi, E.-W., Zheng, Y.-Q., Li, W.-J., Xiao, B., and Zhuang, J.-Y., J. Cryst. Growth, 2003, Vol. 249, No. 1, p. 294. DOI: 10.1016/S0022-0248(02)02154-1.

    Article  CAS  Google Scholar 

  16. Yu, W., Xie, H., Chen, L., Li, Y., and Zhang, C., Nanoscale Res. Lett., 2009, Vol. 4, No. 5, p. 465. DOI: 10.1007/s11671-009-9264-3.

    Article  CAS  Google Scholar 

  17. Xiong, J., Wang, Y., Xue, Q., and Wu, X., Green Chem., 2011, Vol. 13, No. 4, p. 900. DOI: 10.1039/C0GC00772B.

    Article  CAS  Google Scholar 

  18. Diaz-Visurraga, J., Daza, C., Pozo, C., Becerra, A., Plessing, C., and Garcia, A., Int. J. Nanomedicine, 2012, Vol. 7, p. 3597. DOI: 10.2147/IJN.S32648.

    Article  CAS  Google Scholar 

  19. Lur’e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook of Analytical Chemistry), Moscow: Khimiya, 1971.

    Google Scholar 

  20. Stankovich, M.T., Schopfer, L.M., and Massey, V., J. Biol. Chem., 1978, Vol. 253, No. 14, p. 4971.

    CAS  Google Scholar 

  21. Saikova, S.V., Murasheva, K.S., Vorob’ev, S.A., Kochmarev, K.Yu., Karimov, E.E., Eremina, N.D., and Mikhlin, Yu.L., Khim. Inter. Ustoich. Razv., 2013, Vol. 21, No. 4, p. 425.

    CAS  Google Scholar 

  22. Creighton, A.J. and Eadon, D.G., J. Chem. Soc. Faraday Trans., 1991, Vol. 87, No. 24, p. 3881. DOI: 10.1039/FT9918703881.

    Article  CAS  Google Scholar 

  23. Johnson, R.C., Li, J., Hupp, J.T., and Schatz, G.C., Chem. Phys. Lett., 2002, Vol. 356, No. 5, p. 534. DOI: 10.1016/S0009-2614(02)00407-4.

    Article  CAS  Google Scholar 

  24. Saikova, S.V., Vorob’ev, S.A., Nikolaeva, R. B., and Mikhlin, Yu.L., Russ. J. Gen. Chem., 2010, Vol. 80, No. 6, p. 1122. DOI: 10.1134/S1070363210060149.

    Article  CAS  Google Scholar 

  25. The International Center for Diffraction Data: Powder Diffraction File, JCPDS, 2001, no. 00-005-0667.

  26. Wang, Zh.., Chen, X.Y., and Liu, J.W., Solid State Commun., 2004, Vol. 130, No. 9, p. 585. DOI: 10.1016/j.ssc.2004.03.028.

    Article  CAS  Google Scholar 

  27. Vorob’ev, S.A., Cand. Sci. (Chem.) Dissertation, Krasnoyarsk, 2013.

    Google Scholar 

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Authors and Affiliations

  1. Siberian Federal University, pr. Svobodnyi 79, Krasnoyarsk, 660041, Russia

    K. S. Murasheva, K. Yu. Kochmarev, S. A. Vorob’ev & S. V. Saikova

Authors
  1. K. S. Murasheva
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  2. K. Yu. Kochmarev
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  3. S. A. Vorob’ev
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  4. S. V. Saikova
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Correspondence to S. V. Saikova.

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Original Russian Text © K.S. Murasheva, K.Yu. Kochmarev, S.A. Vorob’ev, S.V. Saikova, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 8, pp. 1233–1240.

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Murasheva, K.S., Kochmarev, K.Y., Vorob’ev, S.A. et al. Preparation and study of concentrated hydrosols of copper nanoparticles using of weak reducing agents. Russ J Gen Chem 85, 1793–1800 (2015). https://doi.org/10.1134/S1070363215080010

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  • DOI: https://doi.org/10.1134/S1070363215080010

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