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Preparation and structure of tri-p-tolylbismuth dibromide

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Abstract

Interaction of tri-p-tolylbismuth with bromine in carbon tetrachloride has yielded tri-p-tolylbismuth dibromide. According to X-ray diffraction studies, bismuth atoms in both symmetrically independent dibromide molecules were in distorted trigonal bipyramid surrounding with equatorial aryl substituents.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, ul. Lenina 104, Blagoveshchensk, 675000, Russia

    I. V. Egorova, V. V. Zhidkov, I. P. Grinishak & A. A. Rezvanova

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  1. I. V. Egorova
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  2. V. V. Zhidkov
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  3. I. P. Grinishak
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  4. A. A. Rezvanova
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Correspondence to I. V. Egorova.

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Original Russian Text © I.V. Egorova, V.V. Zhidkov, I.P. Grinishak, A.A. Rezvanova, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 7, pp. 1179–1182.

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Egorova, I.V., Zhidkov, V.V., Grinishak, I.P. et al. Preparation and structure of tri-p-tolylbismuth dibromide. Russ J Gen Chem 84, 1374–1377 (2014). https://doi.org/10.1134/S1070363214070226

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  • DOI: https://doi.org/10.1134/S1070363214070226

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