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Influence of acid-base properties of oxides surface on their reactivity towards epoxy compounds

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Abstract

Acid-base properties of surface of aluminum, iron, and silicon oxides have been studied by pK spectroscopy. γ-Al2O3 and γ-AlO(OH) have been found the most reactive modifiers for epoxy oligomers, due to the presence of active surface groups with pK1 ≈ 4, capable of chemical interaction with the matrix.

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Authors and Affiliations

  1. Institute of Chemistry, Komi Scientific Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, 167000, Russia

    P. A. Sitnikov, A. V. Kuchin, M. A. Ryazanov, A. G. Belykh & I. N. Vaseneva

  2. Institute of Technical Chemistry, Ural Branch, Russian Academy of Sciences, Perm, Russia

    M. S. Fedoseev & V. V. Tereshatov

Authors
  1. P. A. Sitnikov
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  2. A. V. Kuchin
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  3. M. A. Ryazanov
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  4. A. G. Belykh
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  5. I. N. Vaseneva
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  6. M. S. Fedoseev
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  7. V. V. Tereshatov
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Correspondence to P. A. Sitnikov.

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Original Russian Text © P.A. Sitnikov, A.V. Kuchin, M.A. Ryazanov, A.G. Belykh, I.N. Vaseneva, M.S. Fedoseev, V.V. Tereshatov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 5, pp. 717–722.

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Sitnikov, P.A., Kuchin, A.V., Ryazanov, M.A. et al. Influence of acid-base properties of oxides surface on their reactivity towards epoxy compounds. Russ J Gen Chem 84, 810–815 (2014). https://doi.org/10.1134/S107036321405003X

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  • DOI: https://doi.org/10.1134/S107036321405003X

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