Abstract
Colloid particles of metals of varying valence are found to be relatively cheap and easily prepared catalyst permitting the the hydrogenation under mild conditions. Procedure of reduction of unsaturated compounds with gaseous hydrogen at atmospheric pressure and low temperaturehas been developed. Colloid solutions of metals from the series iron, nickel, cobalt, chromium, manganese or their mixtures were prepared in situ directly in the reaction mixture. Selective the hydrogenation of multiple carbon-carbon bonds without the reduction of a series of functional groups was observed.
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Popov, Yu.V., Mokhov, V.M., and Nebykov, D.N., Russ. J. Gen. Chem., 2014, vol. 84, no. 3, p. 444.
Augustine, R.L., Catalytic The hydrogenation, New York: Marcel Dekker, 1965, ch. 4, pp. 38, 135.
Rylander, P.N., Catalytic The hydrogenation over Platinum Metals, New York: Academic Press, 1967, ch. 4, p. 71.
Kalbasi, R.J., Nourbakhsh, A.A., and Badaknezhad, F., Catalysis Commun., 2011, vol. 12, p. 955.
Deghedi, L., Basset, J.M., Candy, J.P., Dalmon, J.A., Dubreuil, A.C., and Fischer, L., Chem. Ing. Trans., 2009, vol. 17, p. 31.
Belykh, L.B., Titova, Yu.Yu., Rokhin, A.V., and Shmidt, F.K., Russ. J. Appl. Chem., 2010, vol. 83, no. 11, p. 1911.
Hosahalli, P., Hemantha, H.P., Vommina, V., and Sureshbabu, V.V., Org. Biomol. Chem., 2011, vol. 9, p. 2597.
Alonso, F., Osantey, I., and Yus, M., Tetrahedron, 2007, vol. 63, p. 93.
Alonso, F., Candela, P., Gomez, C., and Yus, M., Adv. Synth. Catal., 2003, vol. 345, nos. 1–2, p. 275.
Rangheard, C., de Julian Fernandez, C., Pim-Huat Phua, Hoorn, J., Lefort, L., and de Vries, J.G., Dalton Trans., 2010, vol. 39, p. 8464.
In Soo Park, Min Serk Rwon, Kyung Yeon Kang, Jae Sung Lee, and Jaiwook Park, Adv. Synth. Catal., 2007, vol. 349, p. 2039.
Polshettiwar, V., Baruwati, B., and Varma, R.S., Green Chem., 2009, vol. 11, p. 127.
Topchiev, A.V., Pokrovskaya, E.S., and Stepanyseva, T.G., Russ. Chem. Bull., 1958, vol. 8, no. 11, p. 1887.
Schleyer, P.R., Donaldson, M.M., Nicholas, R.D., and Cupas, C., Org. Synth., 1962, vol. 42, p. 9.
Khimicheskaya entsiklopediya (Chemical Encyclopedy), Knunyants, I.L., Ed., Moscow: Sovetskaya Entsiklopediya, 1988, vol. 2, p. 438.
Bruson, H.A. and Reiner, T.W., J. Am. Chem. Soc., 1948, vol. 70, no. 8, p. 2809.
Oldenziel, O.H., van Leusen, D., and van Leusen, A.M., J. Org. Chem., 1977, vol. 42, no. 19, p. 3114.
Bartlett, P.D. and Pincock, R.E., J. Am. Chem. Soc., 1962, vol. 84, no. 12, p. 2445.
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Original Russian Text © V.M. Mokhov, Yu.V. Popov, D.N. Nebykov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 4, pp. 541–547.
For communication I, see [1].
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Mokhov, V.M., Popov, Y.V. & Nebykov, D.N. Colloid and nanodimensional catalysts in organic synthesis: II. The hydrogenation of alkenes with hydrogen at atmospheric pressure. Russ J Gen Chem 84, 622–628 (2014). https://doi.org/10.1134/S1070363214040033
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DOI: https://doi.org/10.1134/S1070363214040033