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Colloid and nanodimensional catalysts in organic synthesis: II. The hydrogenation of alkenes with hydrogen at atmospheric pressure

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Abstract

Colloid particles of metals of varying valence are found to be relatively cheap and easily prepared catalyst permitting the the hydrogenation under mild conditions. Procedure of reduction of unsaturated compounds with gaseous hydrogen at atmospheric pressure and low temperaturehas been developed. Colloid solutions of metals from the series iron, nickel, cobalt, chromium, manganese or their mixtures were prepared in situ directly in the reaction mixture. Selective the hydrogenation of multiple carbon-carbon bonds without the reduction of a series of functional groups was observed.

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References

  1. Popov, Yu.V., Mokhov, V.M., and Nebykov, D.N., Russ. J. Gen. Chem., 2014, vol. 84, no. 3, p. 444.

    Article  CAS  Google Scholar 

  2. Augustine, R.L., Catalytic The hydrogenation, New York: Marcel Dekker, 1965, ch. 4, pp. 38, 135.

    Google Scholar 

  3. Rylander, P.N., Catalytic The hydrogenation over Platinum Metals, New York: Academic Press, 1967, ch. 4, p. 71.

    Google Scholar 

  4. Kalbasi, R.J., Nourbakhsh, A.A., and Badaknezhad, F., Catalysis Commun., 2011, vol. 12, p. 955.

    Article  CAS  Google Scholar 

  5. Deghedi, L., Basset, J.M., Candy, J.P., Dalmon, J.A., Dubreuil, A.C., and Fischer, L., Chem. Ing. Trans., 2009, vol. 17, p. 31.

    Google Scholar 

  6. Belykh, L.B., Titova, Yu.Yu., Rokhin, A.V., and Shmidt, F.K., Russ. J. Appl. Chem., 2010, vol. 83, no. 11, p. 1911.

    Article  CAS  Google Scholar 

  7. Hosahalli, P., Hemantha, H.P., Vommina, V., and Sureshbabu, V.V., Org. Biomol. Chem., 2011, vol. 9, p. 2597.

    Article  Google Scholar 

  8. Alonso, F., Osantey, I., and Yus, M., Tetrahedron, 2007, vol. 63, p. 93.

    Article  CAS  Google Scholar 

  9. Alonso, F., Candela, P., Gomez, C., and Yus, M., Adv. Synth. Catal., 2003, vol. 345, nos. 1–2, p. 275.

    Article  CAS  Google Scholar 

  10. Rangheard, C., de Julian Fernandez, C., Pim-Huat Phua, Hoorn, J., Lefort, L., and de Vries, J.G., Dalton Trans., 2010, vol. 39, p. 8464.

    Article  CAS  Google Scholar 

  11. In Soo Park, Min Serk Rwon, Kyung Yeon Kang, Jae Sung Lee, and Jaiwook Park, Adv. Synth. Catal., 2007, vol. 349, p. 2039.

    Article  CAS  Google Scholar 

  12. Polshettiwar, V., Baruwati, B., and Varma, R.S., Green Chem., 2009, vol. 11, p. 127.

    Article  CAS  Google Scholar 

  13. Topchiev, A.V., Pokrovskaya, E.S., and Stepanyseva, T.G., Russ. Chem. Bull., 1958, vol. 8, no. 11, p. 1887.

    Article  Google Scholar 

  14. Schleyer, P.R., Donaldson, M.M., Nicholas, R.D., and Cupas, C., Org. Synth., 1962, vol. 42, p. 9.

    Google Scholar 

  15. Khimicheskaya entsiklopediya (Chemical Encyclopedy), Knunyants, I.L., Ed., Moscow: Sovetskaya Entsiklopediya, 1988, vol. 2, p. 438.

    Google Scholar 

  16. Bruson, H.A. and Reiner, T.W., J. Am. Chem. Soc., 1948, vol. 70, no. 8, p. 2809.

    Article  CAS  Google Scholar 

  17. Oldenziel, O.H., van Leusen, D., and van Leusen, A.M., J. Org. Chem., 1977, vol. 42, no. 19, p. 3114.

    Article  CAS  Google Scholar 

  18. Bartlett, P.D. and Pincock, R.E., J. Am. Chem. Soc., 1962, vol. 84, no. 12, p. 2445.

    Article  CAS  Google Scholar 

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Correspondence to V. M. Mokhov.

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Original Russian Text © V.M. Mokhov, Yu.V. Popov, D.N. Nebykov, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 4, pp. 541–547.

For communication I, see [1].

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Mokhov, V.M., Popov, Y.V. & Nebykov, D.N. Colloid and nanodimensional catalysts in organic synthesis: II. The hydrogenation of alkenes with hydrogen at atmospheric pressure. Russ J Gen Chem 84, 622–628 (2014). https://doi.org/10.1134/S1070363214040033

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  • DOI: https://doi.org/10.1134/S1070363214040033

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