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Terbium-containing copolymers based on the norbornene functional derivatives. Synthesis, photoluminescent and electroluminescent properties

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Abstract

New carbazole- and terpyridine- containing norbornene derivatives were synthesized and structurally characterized. On the basis of these compounds by the method of metathesis polymerization copolymers were obtained with carbazole and terpyridine fragments in side chains. The synthesized copolymers react with terbium pyrazolonate complex to form the terbium-containing polymeric materials exhibiting the metalcentered photo- and electroluminescence.

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References

  1. Buchmeiser, M.R., Chem. Rev., 2000, vol. 100, no. 4, p. 1565.

    Article  CAS  Google Scholar 

  2. Bielawski, C.W. and Grubbs, R.H., Prog. Polym. Sci., 2007, vol. 32, no. 1, p. 1.

    Article  CAS  Google Scholar 

  3. Schrock, R.R. and Czekelius, C., Adv. Synth. Catal., 2007, vol. 349, no. 1, p. 55.

    Article  CAS  Google Scholar 

  4. Highly Efficient OLEDs with Phosphorescent Materials, Yersin, H., Ed., Weinheim: Wiley-VCH Verlag GmbH & Co KGaA, 2008, p. 456.

    Google Scholar 

  5. Bochkarev, M.N., Vitukhnovskii, A.G., and Katkova, M.A., Organicheskie svetoizluchayushchie diody (Organic Lght Emitting Diodes), Nizhny Novgorod: Dekom, 2011.

    Google Scholar 

  6. Cho, J.-Y., Domercq, B., Barlow, S., Suponitsry, R.Yu., Li, J., Timofeeva, T.V., Jones, S.C., Hayden, L.E., Kimyonok, A., South, C.R., Weck, M., Kippelen, B., and Marder, S.R., Organometallics., 2007, vol. 26, no. 19, p. 4816.

    Article  CAS  Google Scholar 

  7. Begantsova, Y.E., Bochkarev, L.N., Malysheva, I.P., Stolyarova, N.E., Kurskii, Yu.A., Lopatin, M.A., Baranov, E.V., Ilichev, V.A., Abakumov, G.A., and Bochkarev, M.N., Synthetic Metals, 2011, vol. 161, no. 12, p. 1043.

    Article  CAS  Google Scholar 

  8. Kimyonok, A., Domercq, B., Haldi, A., Cho Jian-Yang, Carlise, J.R., Wang Xiang-Yong, Hayden, L.E., Jones, S.C., Barlow, S., Marder, S.R., Kippelen, B., and Weck, M., Chem. Mater., 2007, vol. 19, no. 23, p. 5602.

    Article  CAS  Google Scholar 

  9. Bochkarev, L.N., Safronova, A.V., and Basova, G.V., Zh. Obshch. Khim., 2010, vol. 80, no. 4, p. 535.

    Google Scholar 

  10. Li, X.-L., Dai, F.-R., Zhang, L.-Y., Zhu, Y.-M., Peng, Q., and Chen, Z.-N., Organometallics, 2007, vol. 26, no. 18, p. 4483.

    Article  CAS  Google Scholar 

  11. Xin, H., Shi, M., Zhang, X.M., Li, F.Y., Bian, Z.Q., Ibrahim, K., Liu, F.Q., and Huang, C.H., Chem. Mater., 2003, vol. 15, no. 19, p. 3728.

    Article  CAS  Google Scholar 

  12. Chen, Z., Ding, F., Hao, F., Bian, Z., Ding, B., Zhu, Y., Chen, F., and Huang, C., Org. Electr., 2009, vol. 10, no. 5, p. 939.

    Article  CAS  Google Scholar 

  13. Roberts, J.D., Trumbull, E.R., Bennet, W., and Armstrong, R., J. Am. Chem. Soc., 1950, vol. 72, no. 7, p. 3116.

    Article  CAS  Google Scholar 

  14. Allen, F.H., Kennard, O., Watson, D.G., Brammer, L., Orpen, A.G., and Taylor, R., J. Chem. Soc., Perkin Trans. 2., 1987, vol. 12, no. 12, p. 1.

    Article  Google Scholar 

  15. Pollino, J.M., Stubbs, L.P., and Weck, M., Macromolecules, 2003, vol. 36, no. 7, p. 2230.

    Article  CAS  Google Scholar 

  16. Hoyle, C.E., Nemzek, T.L., Mar, A., and Guillet, J.E., Macromolecules, 1978, vol. 11, no. 2, p. 429.

    Article  CAS  Google Scholar 

  17. Förster, T., Discuss Faraday Soc., 1959, vol. 27, no. 1, p. 7.

    Article  Google Scholar 

  18. Wilson, J.S., Chawdhury, N., Al-Mandhary, M.R.A., Younus, M., Khan, M.S., Raithby, P.R., Köhler, A., and Friend, R.H., J. Am. Chem. Soc., 2001, vol. 123, no. 38, p. 9412.

    Article  CAS  Google Scholar 

  19. Partee, J., Frankevich, E.L., Uhlhorn, B., Shinar, J., Ding, Y., and Barton, J.T., Phys. Rev. Lett., 1999, vol. 82, no. 18, p. 3673.

    Article  CAS  Google Scholar 

  20. Binnemans, K., Chem. Rev., 2009, vol. 109, no. 9, p. 4283.

    Article  CAS  Google Scholar 

  21. Potts, K.T. and Konwar, D., J. Org. Chem., 1991, vol. 56, no. 15, p. 4815.

    Article  CAS  Google Scholar 

  22. Parham, W.E., Hunter, W.T., and Hanson, R., J. Am. Chem. Soc., 1951, vol. 73, no. 11, p. 5068.

    Article  CAS  Google Scholar 

  23. Mehrotra, R.C. and Batwara, J.M., Inorg. Chem., 1970, vol. 11. no. 10, p. 2505.

    Article  Google Scholar 

  24. Scholl, M., Ding, S., Lee, C.W., and Grubbs, R.H., Org. Lett., 1999, vol. 1, no. 6, p. 953.

    Article  CAS  Google Scholar 

  25. Love, J.A., Morgan, J.P., Trnka, T.M., and Grubbs, R.H., Angew. Chem. Int. Ed., 2002, vol. 41, no. 21, p. 4035.

    Article  CAS  Google Scholar 

  26. Li, B., Miao, W.R., and Cheng, L.B., Dyes Pigments., 1999, vol. 43, no. 2, p. 161.

    Article  CAS  Google Scholar 

  27. Demas, J.N. and Crosby, G.A., J. Phys. Chem., 1971, vol. 75, no. 8, p. 991.

    Article  Google Scholar 

  28. SAINTPlus Data Reduction and Correction Program, v. 6.02a; Bruker AXS: Madison, WI, 2000.

  29. Sheldrick, G.M., SHELXTL. v. 6.12, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin (USA), 2000.

    Google Scholar 

  30. Sheldrick, G.M., SADABS. v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin (USA), 1998.

    Google Scholar 

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Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, ul. Tropinina 49, Nizhny Novgorod, 603950, Russia

    A. V. Rozhkov, L. N. Bochkarev, G. V. Basova, I. P. Malysheva, Yu. E. Begantsova, E. O. Platonova, E. V. Baranov, Yu. A. Kurskii, V. A. Il’ichev, M. A. Lopatin, G. A. Abakumov & M. N. Bochkarev

Authors
  1. A. V. Rozhkov
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  2. L. N. Bochkarev
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  3. G. V. Basova
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  4. I. P. Malysheva
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  5. Yu. E. Begantsova
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  6. E. O. Platonova
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  7. E. V. Baranov
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  8. Yu. A. Kurskii
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  9. V. A. Il’ichev
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  10. M. A. Lopatin
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  11. G. A. Abakumov
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  12. M. N. Bochkarev
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Correspondence to L. N. Bochkarev.

Additional information

Original Russian Text © A.V. Rozhkov, L.N. Bochkarev, G.V. Basova, I.P. Malysheva, Yu.E. Begantsova, E.O. Platonova, E.V. Baranov, Yu.A. Kurskii, V.A. Il’ichev, M.A. Lopatin, G.A. Abakumov, M.N. Bochkarev, 2012, published in Zhurnal Obshchei Khimii, 2012, Vol. 82, No. 12, pp. 1937–1950.

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Rozhkov, A.V., Bochkarev, L.N., Basova, G.V. et al. Terbium-containing copolymers based on the norbornene functional derivatives. Synthesis, photoluminescent and electroluminescent properties. Russ J Gen Chem 82, 1895–1908 (2012). https://doi.org/10.1134/S1070363212120018

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  • DOI: https://doi.org/10.1134/S1070363212120018

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