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Synthesis and properties of Cu(II) and Pd(ii) complexes with chiral bis-α-sulfanyl oxymes, the derivatives of natural monoterpene, α-pinene

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Abstract

Coordination compounds Cu2(H2L1)Cl4 (I), Pd2(H2L1)Cl4 (II), Cu2(H2L2)Cl4 (III), and Pd2(H2L2) Cl4 (IV) with chiral bis-α-sulfanyloximes, the derivatives of the monoterpenoid (−)-α-pinene, were obtained. The complexes I and III are paramagnetic (μeff = 2.45 and 2.67 μB, respectively), II and IV are diamagnetic. According to IR spectroscopy, in the compounds I–IV the nearest environment of Cu and Pd atoms includes N, S, and Cl atoms. The values of μeff and parameters of ESR spectra of the solid phase and solutions of I and III show a binuclear structure of the Cu(II) complexes. Parameters of the 1H and 13C NMR spectra of compounds II and IV indicate the formation of binuclear Pd(II) complexes of C 2 symmetry and the closure of fivemembered chelate rings PdNSC2. The PdCl2 fragments are in transoid position. H2L1 and H2L2 are tetradentate bridging chelating ligands.

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References

  1. Von Zelewsky, A. and Mamula, O., Dalton Trans., 2000, no. 3, p. 219.

  2. Mamula, O. and von Zelewsky, A., Coord. Chem. Rev., 2003, vol. 242, p. 87.

    Article  CAS  Google Scholar 

  3. Tkachev, A.V., Ros. Khim. Zh., 1998, vol. 42, nos. 1–2, p. 42.

    CAS  Google Scholar 

  4. Larionov, S.V. and Tkachev, A.V., Ros. Khim. Zh., 2004, vol. 48, no. 4, p. 154.

    CAS  Google Scholar 

  5. Larionov, S.V., Myachina, L.I., Glinskaya, L.A., Klevtsova, R.F., Sheludyakova, L.A., Tkachev, A.V., and Bizyaev, S.N., Koord. Khim., 2003, vol. 29, no. 11, p. 857.

    Google Scholar 

  6. Larionov, S.V., Myachina, L.I., Sheludyakova, L.A., Boguslavskii, E.G., Tkachev, A.V., and Bizyaev, S.N., Koord. Khim., 2004, vol. 30, no. 11, p. 827.

    Google Scholar 

  7. Larionov, S.V., Myachina, L.I., Savel’eva, Z.A., Glinskaya, L.A., Klevtsova, R.F., Sheludyakova, L.A., Tkachev, A.V., and Bizyaev, S.N., Koord. Khim., 2004, vol. 30, no. 12, p. 888.

    Google Scholar 

  8. Larionov, S.V., Savel’eva, Z.A., Glinskaya, L.A., Klevtsova, R.F., Bizyaev, S.N., and Tkachev, A.V., Zh. Strukt. Khim., 2005, vol. 46, no. 3, p. 558.

    Google Scholar 

  9. Larionov, S.V., Tkachev, A.V., Savel’eva, Z.A., Myachina, L.I., Glinskaya, L.A., Klevtsova, R.F., and Bizyaev, S.N., Koord. Khim., 2006, vol. 32, no. 4, p. 261.

    Google Scholar 

  10. Larionov, S.V., Savel’eva, Z.A., Glinskaya, L.A., Klevtsova, R.F., Sheludyakova, L.A., Bizyaev, S.N., and Tkachev, A.V., Koord. Khim., 2006, vol. 32, no. 5, p. 365.

    Google Scholar 

  11. Savel’eva, Z.A., Bizyaev, S.N., Glinskaya, L.A., Klevtsova, R.F., Tkachev, A.V., and Larionov, S.V., Koord. Khim., 2006, vol. 32, no. 10, p. 754.

    Google Scholar 

  12. Savel’eva, Z.A., Klevtsova, R.F., Glinskaya, L.A., Ikorskii, V.N., Bizyaev, S.N., Tkachev, A.V., and Larionov, S.V., Koord. Khim., 2006, vol. 32, no. 11, p. 816.

    Google Scholar 

  13. Kokina, T.E., Myachina, L.I., Glinskaya, L.A., Tkachev, A.V., Klevtsova, R.F., Sheludyakova, L.A., Bizyaev, S.N., Agafontsev, A.M., Gorshkov, S.N., and Larionov, S.V., Koord. Khim., 2008, vol. 34, no. 2, p. 120.

    Google Scholar 

  14. Larionov, S.V., Kokina, T.E., Agafontsev, A.M., Gorshkov, N.B., Tkachev, A.V., Klevtsova, R.F., and Glinskaya, L.A., Koord. Khim., 2007, vol. 33, no. 7, p. 525.

    Google Scholar 

  15. Polyanskaya, E.V., Abstract of Papers, 46th Int. Sci. Students’ Conf. “Student and Progress in Science and Technology,” Novosibirsk: Khimiya, 2008, p.37.

    Google Scholar 

  16. Singh, R.V., Fahmi, N., and Biyala, M.K., J. Iranian Chem. Soc., 2005, vol. 2, no. 1, p. 40.

    CAS  Google Scholar 

  17. Kokina, T.E., Klevtsova, R.F., Glinskaya, L.A., Agafontsev, A.M., Tkachev, A.V., and Larionov, S.V., Zh. Neorg. Khim., 2008, vol. 53, no. 5, p.758.

    CAS  Google Scholar 

  18. Myachina, L.I., Tkachev, A.V., G.V. Romanenko, Sheludyakova, L.A., Boguslavskii, E.G., and Larionov, S.V., Koord. Khim., 2003, vol. 29, no. 8, p.611.

    Google Scholar 

  19. Gorshkov, N.B., Agafontsev, A.M., and Tkachev, A.V., Izv. Akad. Nauk, Ser. Khim., 2010, no. 10, p. 1434.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    T. E. Kokina, L. A. Sheludyakova, E. G. Boguslavskii & S. V. Larionov

  2. Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Tkachev, A. M. Agafontsev & N. B. Gorshkov

Authors
  1. T. E. Kokina
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  2. L. A. Sheludyakova
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  3. A. V. Tkachev
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  4. E. G. Boguslavskii
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  5. A. M. Agafontsev
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  6. N. B. Gorshkov
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  7. S. V. Larionov
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Correspondence to T. E. Kokina.

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Original Russian Text © T.E. Kokina, L.A. Sheludyakova, A.V. Tkachev, E.G. Boguslavskii, A.M. Agafontsev, N.B. Gorshkov, S.V. Larionov, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 8, pp. 1306–1312.

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Kokina, T.E., Sheludyakova, L.A., Tkachev, A.V. et al. Synthesis and properties of Cu(II) and Pd(ii) complexes with chiral bis-α-sulfanyl oxymes, the derivatives of natural monoterpene, α-pinene. Russ J Gen Chem 81, 1651–1657 (2011). https://doi.org/10.1134/S1070363211080123

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  • DOI: https://doi.org/10.1134/S1070363211080123

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