Abstract
Molar volumes in solutions of compounds like orthoformic esters, trialkyl phosphates, trialkylphosphites, substituted aziridines, cyclopropanes, cyclohexanes, boroxines, N-aryl-4-pyridones, decalines, and cyclooctane were determined and discussed. Conformations of alkyl substituents in the esters were found to be similar to the conformations of the corresponding alkanes. Molar volumes of aziridines and cyclopropanes were found to be additive with respect to the molar volumes of bond and group increments. The nature of solvation of the molecules of these compounds was found to be similar to that in the model systems which served for the calculations of the increments. Molar volumes of cyclohexane, decaline, and cyclooctane also were found to be additive with respect to the contributions of the molar volumes of increments of the corresponding bonds and groups. The solvation and the steric structure of substituted boroxines were found to be similar to those of the structurally analogous substituted benzenes. Conformations of N-aryl-4-pyridone and its substituted derivatives in solutions were found to be similar to the conformations of biphenyl and its derivatives. A possibility of simplification of the methods for determining the dipole moments and Kerr constants of compounds from their additive molar volumes was demonstrated.
Similar content being viewed by others
References
Bulgarevich, S.B., Boiko, M.V., Lyashenko, M.N., and Akimova, E.E., Zh. Obshch. Khim., 2010, vol. 80, no. 11, p. 1884.
Aroney, M.J., Le Fevre, R.J.W, and Singh, A.N., J. Chem. Soc., 1964, no. 11, p. 3523.
Aroney, M.J., Chia, L.H.L., Le Fevre, R.J.W., and Saxby J.D., J. Chem. Soc., 1964, no. 9, p. 2948.
Armstrong, R.S., Aroney, M.J., Le Fevre, R.J.W., Stootman, H.J., and Lüttke, W., J. Chem. Soc., B, 1971, no. 11, p. 2104.
Armstrong, R.S., Aroney, M.J., Hector, A., Hopkins, P., Le Fevre, R.J.W., and Lüttke, W., J. Chem. Soc., B, 1971, no. 7, p. 1499.
Aroney, M.J., Calderbank, K.E., Stootman, H.J., J. Chem. Soc., Perkin Trans 2, 1973, no. 15, p. 2060.
Le Fevre, R.J.W., Orr, B.J., and Ritchie, G.L.D., J. Chem. Soc., B, 1966, no. 3, p. 273.
Aroney, M.J., Le Fevre, R.J.W., Murthy, D.S.N., and Saxby, J.D., J. Chem. Soc., B, 1966, no. 11, p. 1066.
Batts, B.D., Le Fevre, R.J.W., and Madeley, A.J., Aust. J. Chem., 1974, vol. 27, no. 10, p. 2275.
Potekhin, A.A., Spravochnik. Svoistva organicheskikh soedinenii (Handbook. Properties of Organic Compounds), Leningrad: Khimiya, 1984.
Bulgarevich, S.B., Burdastykh, T.V., Tishchenko, L.G., and Kosheleva, I.V., Zh. Obshch. Khim., 2005, vol. 75, no. 11, p. 1866.
Bulgarevich, S.B., Burdastykh, T.V., and Tishchenko, L.G., Zh. Obshch. Khim., 2006, vol. 76, no. 6, p. 999.
Bulgarevich, S.B. and Burdastykh, T.V., Zh. Obshch. Khim., 2008, vol. 78, no. 1, p. 118.
Rabinovich, V.A. and Khavin Z.Ya., Kratkii khimicheskii spravochnik (Short Chemical Handbook), Moscow: Khimiya, 1978.
Turova, N.Ya., Spravochnye tablitsy po neorganicheskoi khimii (Reference Tables on Inorganic Chemistry), Leningrad: Khimiya, 1976.
Aroney, M.J. and Pratten, S.J., J. Chem. Soc., Faraday Trans., 1984, vol. 80, no. 5, p. 1201.
Le Fevre, C.G. and Le Fevre, R.J.W., J. Chem. Soc., 1953, no. 12, p. 4041.
Vereshchagin, A.I., Polyarizuemost’ molekul (Polymerizability of Molecules), Moscow: Nauka, 1980.
Green, R.W., Le Fevre, R.J.W., and Saxby, J.D., Aust. J. Chem., 1966, vol. 19, no. 11, p. 2007.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.B. Bulgarevich, M.V. Boiko, M.N. Lyashenko, E.E. Akimova, 2011, published in Zhurnal Obshchei Khimii, 2011, Vol. 81, No. 7, pp. 1163–1174.
For communication LV, see [1].
Rights and permissions
About this article
Cite this article
Bulgarevich, S.B., Boiko, M.V., Lyashenko, M.N. et al. Molecular polarizability of organic compounds and their complexes: LVI. Molar volume and structure in a solution of the compounds with several axes of intramolecular rotation. Russ J Gen Chem 81, 1511 (2011). https://doi.org/10.1134/S1070363211070176
Received:
Published:
DOI: https://doi.org/10.1134/S1070363211070176