Skip to main content
SpringerLink
Log in

Atropoisomerism of 13-N,N-dimethylamide-15,17-dimethyl ester of chlorin e 6 from the data of X-ray, 1H NMR, and HPLC

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Atropoisomerism of tertiary 13-amides of chlorin e 6 was studied by the methods of X-ray analysis, 1H NMR spectroscopy, and high performance liquid chromatography on the example of 13-N,N-dimethylamide-15,17-dimethyl ester of chlorin e 6. The spatial structure of the major and minor atropoisomers was established. The possibility of reversible interconversion of the atropoisomers of the studied compound in solution was shown.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Spikes, J.D., J. Photochemistry and Photobiology, Part B: Biology, 1990, vol. 6, p. 259.

    Article  CAS  Google Scholar 

  2. Sternberg, E.D., Dolphin, D., and Bruckner, C., Tetrahedron., 1998, vol. 54, p. 4151.

    Article  CAS  Google Scholar 

  3. Nyman, E.S. and Hynninen, P.H., J. Photochemistry and Photobiology, Part B: Biology, 2004, vol. 73, p. 1.

    Article  CAS  Google Scholar 

  4. Bregadze, V.I., Sivaev, I.B., Gabel, D., and Wohrle, D., J. Porphyrins and Phthalocyanines, 2001, vol. 5, p. 767.

    Article  CAS  Google Scholar 

  5. Ol’shevskaya, V.A., Nikitina, R.G., Savchenko, A.N., Malshakova, M.V., Vinogradov, A.M., Golovina, G.V., Belykh, D.V., Kutchin, A.V., Kaplan, M.A., Kalinin, V.N., Kuzmin, V.A., and Shtil, A.A., Bioorganic & Medicinal Chemistry, 2009, vol. 17, p. 1297.

    Article  Google Scholar 

  6. Belykh, D.V., Karmanova, L.P., Spirikhin, L.V., and Kutchin, A.V., Mendeleev Commun., 2002, vol. 12, p. 77.

    Article  Google Scholar 

  7. Belykh, D.V., Karmanova, L.P., Spirikhin, L.V., and Kutchin, A.V., Russ. J. Org. Chem., 2007, vol. 43, no. 1, p. 126.

    Article  CAS  Google Scholar 

  8. Belykh, D.V., Tarabukina, I.S., Matveev, Yu.S., and Kutchin, A.V., Russ. J. Gen. Chem., 2007, vol. 77, no. 7, p. 1300.

    Article  CAS  Google Scholar 

  9. Sheldrick, G.M., Acta Crystallogr. Sect. A, 2008, vol. 64, p. 112.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry of Komi Scientific Center, Ural Branch, Russian Academy of Sciences, ul. Pervomaiskaya 48, Syktyvkar, GSP-2, 167982, Russia

    D. V. Belykh, E. V. Buravlev, P. A. Slepukhin & A. V. Kuchin

  2. Postovskii Institute of Organic Synthesis, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 22, Yekaterinburg, 620041, Russia

    D. V. Belykh, E. V. Buravlev, P. A. Slepukhin & A. V. Kuchin

Authors
  1. D. V. Belykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. V. Buravlev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. A. Slepukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. V. Kuchin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. V. Belykh.

Additional information

Original Russian Text © D.V. Belykh, E.V. Buravlev, P.A. Slepukhin, A.V. Kuchin, 2010, published in Zhurnal Obshchei Khimii, 2010, Vol. 80, No. 11, pp. 1919–1923.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Belykh, D.V., Buravlev, E.V., Slepukhin, P.A. et al. Atropoisomerism of 13-N,N-dimethylamide-15,17-dimethyl ester of chlorin e 6 from the data of X-ray, 1H NMR, and HPLC. Russ J Gen Chem 80, 2382–2386 (2010). https://doi.org/10.1134/S1070363210110241

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363210110241

Keywords

Search

Navigation