Skip to main content
SpringerLink
Log in

Effect of the oxidation state of copper on the solution-solid phase equilibria in CuClx-MCl-H2O systems

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

The effect of the oxidation state of the metal on the solubility was analyzed using the example of CuClx-MCl-H2O (x = 1, 2; M = Li-Cs, NH4) ternary systems. The prevalence of acido complex formation is responsible for an essential similarity of the solubility isotherms: the presence of crystallization branches of complex salts and salting-in (or weak salting-out) of copper(I) and (II) chlorides, that increases in the order LiCl < NaCl < KCl < CsCl. The different stability of copper(I) and (II) chloride complexes results in that the chemical individuality of alkali metal cations is differently reflected in the shape of the solubility isotherms: The stronger complex formation in copper(I) systems results in leveling of this effect and the weaker complex formation with copper(II), in its differentiation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Stepakova, L.V. and Skripkin, M.Yu., Zh. Neorg. Khim., 1999, vol. 44, no. 2, p. 325.

    CAS  Google Scholar 

  2. Skripkin, M.Yu., Chernykh, L.V., Stepakova, L.V., and Samokhvalova, V.A., Zh. Prikl. Khim., 2002, vol. 75, no. 7, p. 1069.

    Google Scholar 

  3. Skripkin, M.Yu., Stepakova, L.V., and Chernykh, L.V., Abstracts of Papers, XII Mezhdunarodnaya Chugaevskaya konferentsiya po koordinatsionnoi khimii (XII Int. Chugaev Conf. on Coordination Chemistry), Kishinev, 2005, p. 497.

  4. Skripkin, M.Yu. and Chernykh, L.V., Zh. Neorg. Khim., 1994, vol. 39, no. 10, p. 1747.

    CAS  Google Scholar 

  5. Chernykh, L.V. and Skripkin, M.Yu., Zh. Obshch. Khim., 1996, vol. 66, no. 1, p. 26.

    CAS  Google Scholar 

  6. Chernykh, L.V. and Skripkin, M.Yu., Koord. Khim., 1996, vol. 22, no. 5, p. 413.

    Google Scholar 

  7. Chernykh, L.V., Eysseltova, J., and Skripkin, M.Yu., Monatsh. Chem., 2003, vol. 134, no. 5, p. 751.

    CAS  Google Scholar 

  8. Kumok, V.N., Kuleshova, O.N., and Karabin, L.A., Proizvedeniya rastvorimosti (Solubility Products), Novosibirsk: Nauka, 1983, p. 266.

    Google Scholar 

  9. Krestov, G.A., Termodinamika ionnykh protsessov v rastvorakh (Thermodynamics of Ionic Processes in Solutions), Leningrad: Khimiya, 1984, p. 112.

    Google Scholar 

  10. Sillen, L.G. and Martell, A.E., Stability Constants of Metal-Ion Complexes: Section 1. Inorganic Ligands, London: Pergamon, 1971, p. 163.

    Google Scholar 

  11. Hanna, F.M., Pethybridge, A.D., and Prue, J.E., Electrochim. Acta, 1971, vol. 16, no. 6, p. 677.

    Article  CAS  Google Scholar 

  12. Berndt, M., International Crystallographic Structural Database ICSD/Retrieve 2.01, Karlsruhe, 2001.

  13. Spravochnik po rastvorimosti (Handbook on Solubility), Kafarov, V.V., Ed., Leningrad: Nauka, 1969, vol. III, book 2.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. St. Petersburg State University, Universitetskii pr. 26, St. Petersburg, 198904, Russia

    L. V. Stepakova, M. Yu. Skripkin, L. V. Chernykh & I. M. Gusev

Authors
  1. L. V. Stepakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Yu. Skripkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. V. Chernykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. M. Gusev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © L.V. Stepakova, M.Yu. Skripkin, L.V. Chernykh, I.M. Gusev, 2006, published in Zhurnal Obshchei Khimii, 2006, Vol. 76, No. 4, pp. 540–544.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stepakova, L.V., Skripkin, M.Y., Chernykh, L.V. et al. Effect of the oxidation state of copper on the solution-solid phase equilibria in CuClx-MCl-H2O systems. Russ J Gen Chem 76, 512–516 (2006). https://doi.org/10.1134/S1070363206040037

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070363206040037

Keywords

Search

Navigation