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The Length of Substituents on Ligands Regulates the Structural Diversity of Coordination Polymers

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Abstract

Three coordination polymers, namely, {[Co(L1)(HBTC)]·0.5L1}n (I), {[Co(L2)(HBTC)]·H2O}n (II), {[Co(L3)(HBTC)]·H2O}n (III), have been synthesized based on three semi-rigid nitrogen-containing ligands (L1 = 4,4'-(2,5-dimethoxy-1,4-phenylene)dipyridine; L2 = 4,4'-(2,5-diethoxy-1,4-phenylene)dipyridine; L3 = 4,4'-(2,5-dibutoxy-1,4-phenylene)dipyridine) and 1,3,5-benzenetricarboxylic acid (H3BTC). Both I and II are a 4-connected uninodal sql net with point symbol {44∙62}, III is a 6-connected uninodal rob net with point symbol {48∙66∙8}. The complexes were characterized by X-ray single-crystal diffraction (CIF files CCDC nos. 2034103 (II), 2034104 (III)), PXRD, IR spectra and TGA. Interestingly, the structural diversity of these complexes derived from the length of substituents on Ln (n = 1, 2, 3) ligands.

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Funding

This work was supported by quality engineering of Anqing Normal University in 2018 (2018aqnujyxm052), anhui provincial quality engineering project in 2019 (2019jyxm0291) and anhui natural science foundation youth project (1908085QB49).

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Authors and Affiliations

  1. AnHui Province Key Laboratory of Optoelectronic and Magnetism Functional Materials, Key Laboratory of Functional Coordination Compounds of Anhui Higher Education Institutes, Anqing Normal University, 261433, Anqing, P.R. China

    C. L. Zhang, J. L. Qian & T. Zhou

  2. State Key Laboratory of Polyolefins and Catalysis, Shanghai Key Laboratory of Catalysis Technology for Polyolefins, Shanghai Research Institute of Chemical Industry Co., Ltd., 200062, Shanghai, P.R. China

    Y. Q. Li

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  1. C. L. Zhang
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  2. J. L. Qian
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  3. T. Zhou
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  4. Y. Q. Li
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Correspondence to C. L. Zhang or Y. Q. Li.

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Zhang, C.L., Qian, J.L., Zhou, T. et al. The Length of Substituents on Ligands Regulates the Structural Diversity of Coordination Polymers. Russ J Coord Chem 47, 922–931 (2021). https://doi.org/10.1134/S1070328421120058

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  • DOI: https://doi.org/10.1134/S1070328421120058

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