Skip to main content
Springer Nature Link
Log in

Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

    We’re sorry, something doesn't seem to be working properly.

    Please try refreshing the page. If that doesn't work, please contact support so we can address the problem.

Abstract

The complexes [Tb(Bipy)2(H2O)2Cl2]Cl (I), [Ln(Bipy)(H2O)6]Cl3·2H2O·0.5Bipy (Ln = Dy (II), Yb (IV)), [Er(Bipy)2(H2O)3Cl]Cl2·2H2O (III), and [Yb(Bipy)(H2O)6]Cl3 (V) were prepared using salts LnCl3·6H2O (Ln = Tb, Dy, Er, Yb) and 2,2'-bipyridine (Bipy). The structure of complex V was determined by X-ray diffraction (CIF file CCDC no. 2024688). Magnetic characteristics of the complexes indicate that the replacement of water molecules in the coordination sphere of aqua chlorides by bidentate Bipy ligand gives single-molecule magnets with significant barriers for magnetization reversal, especially in the case of ytterbium compound, ΔE/kB([Yb(Bipy)(H2O)6]Cl3·2H2O·0.5Bipy) = 43 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Gatteschi, D., Villain, J., and Sessoli, R., Molecular Nanomagnets, Oxford: Oxford University, 2006.

    Book  Google Scholar 

  2. Winpenny, R. and Aromí, G., Single-Molecule Magnets and Related Phenomena, Springer, 2006.

    Book  Google Scholar 

  3. Bartolomé, S.J., Luis, F., and Fernandez, J.F., Molecular Magnets: Physics and Applications, Springer, 2014.

    Book  Google Scholar 

  4. Benelli, C. and Gatteschi, D., Introduction to Molecular Magnetism: From Transition Metals to Lanthanides, Wiley, 2015.

    Book  Google Scholar 

  5. Layfield, R.A. and Murugesu, M., Lanthanides and Actinides in Molecular Magnetism, Wiley-VCH, 2015.

    Book  Google Scholar 

  6. Gupta, S.K. and Murugavel, R., Chem. Commun., 2018, vol. 54, p. 3685.

    Article  CAS  Google Scholar 

  7. Feng, M. and Tong, M.-L., Chem.-Eur. J., 2018, vol. 24, p. 7574.

    Article  CAS  PubMed  Google Scholar 

  8. Guo, F.-S., Day, B.M., Chen, Y.-C., et al., Angew. Chem., Int. Ed. Engl., 2017, vol. 56, p. 11445.

    Article  CAS  Google Scholar 

  9. Guo, F.S., Day, B.M., Chen, Y.-C., et al., Angew. Chem., 2017, vol. 129, p. 11603.

    Article  Google Scholar 

  10. Goodwin, C.A.P., Ortu, F., Reta, D., et al., Nature, 2017, vol. 548, p. 439.

    Article  CAS  PubMed  Google Scholar 

  11. Woodruff, D.N., Winpenny, R.E., and Layfield, R.A., Chem. Rev., 2013, vol. 113, p. 5110.

    Article  CAS  PubMed  Google Scholar 

  12. Zhang, P., Zhang, L., and Tang, J., Dalton Trans., 2015, vol. 44, p. 3923.

    Article  CAS  PubMed  Google Scholar 

  13. Lee, S. and Ogawa, T., Chem. Lett., 2017, vol. 46, p. 10.

    Article  CAS  Google Scholar 

  14. Lu, J., Guo, M., and Tang, J., Chem. Asian J., 2017, vol. 12, p. 2772.

    Article  CAS  PubMed  Google Scholar 

  15. McAdams, S.G., Ariciu, A.-M., Kostopoulos, A.K., et al., Coord. Chem. Rev., 2017, vol. 346, p. 216.

    Article  CAS  Google Scholar 

  16. Guo, F.-S., Day, B.M., Chen, Y.C., et al., Science, 2018, vol. 362, p. 1400.

    Article  CAS  PubMed  Google Scholar 

  17. Sessoli, R. and Powell, A.K., Coord. Chem. Rev., 2009, vol. 253, p. 2328.

    Article  CAS  Google Scholar 

  18. Sorace, L., Benelli, C., and Gatteschi, D., Chem. Soc. Rev., 2011, vol. 40, p. 3092.

    Article  CAS  PubMed  Google Scholar 

  19. Guo, Y.-N., Ungur, L., Granroth, G.E., et al., Sci. Rep., 2014, vol. 4, p. 5471.

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  20. Petrosyants, S.P., Dobrokhotova, Zh.V., Ilyukhin, A.B., et al., Eur. J. Inorg. Chem., 2017, p. 3561.

  21. Petrosyants, S.P., Babeshkin, K.A., Gavrikov, A.V., et al., Dalton Trans., 2019, vol. 48, p. 12644.

    Article  CAS  PubMed  Google Scholar 

  22. TOPAS, Karlsruhe (Germany): Bruker AXS, 2005.

  23. APEX II and SAINT, Madison: Bruker AXS Inc., 2007.

  24. Sheldrick, G.M., SADABS, Göttingen: Univ. of Göttingen, 1997.

    Google Scholar 

  25. Sheldrick, G.M., Acta Crystallogr., Sect. C: Struct. Chem., 2015, vol. 71, no. 1, p. 3.

    Article  CAS  Google Scholar 

  26. Petrosyants, S.P., Ilyukhin, A.B., Efimov, N.N., and Novotortsev, V.M., Russ. J. Coord. Chem., 2018, vol. 44, no. 11, p. 660. https://doi.org/10.1134/S1070328418110064

    Article  CAS  Google Scholar 

  27. Petrosyants, S.P., Russ. J. Coord. Chem., 2019, vol. 45, no. 11, p. 749.

    Article  CAS  Google Scholar 

  28. Semenova, L.I., Skelton, B.W., and White, A.H., Aust. J. Chem., 1999, vol. 52, no. 6, p. 551.

    Article  CAS  Google Scholar 

  29. Puntus, L.N., Lyssenko, K.A., Pekareva, I.S., and Bunzli, J.-G., J. Phys. Chem. B, 2009, vol. 113, p. 9265.

    Article  CAS  PubMed  Google Scholar 

  30. Kahn, O., Molecular Magnetism, New York: VCH, 1993.

    Google Scholar 

  31. Pinkowicz, D., Ren, M., Zheng, L.-M., et al., Chem.-Eur. J., 2014, vol. 20, p. 12502.

    Article  CAS  PubMed  Google Scholar 

  32. Gupta, S.K., Rajeshkumar, T., Rajaraman, G., and Murugavel, R., Chem. Commun., 2016, vol. 52, p. 7168.

    Article  CAS  Google Scholar 

  33. Habib, F., Luca, O.R., Vieru, V., et al., Angew. Chem., Int. Ed. Engl., 2013, vol. 52, p. 11290.

    Article  CAS  Google Scholar 

  34. Jeletic, M., Lin, P.H., Le Roy, J.J., et al., J. Am. Chem. Soc., 2011, vol. 133, p. 19286.

    Article  CAS  PubMed  Google Scholar 

  35. Lucaccini, E., Briganti, M., Perfetti, M., et al., Chem.-Eur. J., 2016, vol. 22 P, p. 5552.

  36. Ruiz, J., Mota, A.J., Rodríguez-Diéguez, A., et al., Chem. Commun., 2012, vol. 48, p. 7916.

    Article  CAS  Google Scholar 

  37. Pavlov, A.A., Nelyubina, Y.V., Kats, S.V., et al., J. Phys. Chem. Lett., 2016, vol. 7, no. 20, p. 4111.

    Article  CAS  PubMed  Google Scholar 

  38. Hu, Z.-B., Jing, Z.-Y., Li, M.-M., et al., Inorg. Chem., 2018, vol. 57, p. 10761.

    Article  CAS  PubMed  Google Scholar 

  39. Gavrikov, A.V., Koroteev, P.S., Efimov, N.N., et al., Dalton Trans., 2017, vol. 46, p. 3369.

    Article  CAS  PubMed  Google Scholar 

  40. Li, J., Han, Y., Cao, F., et al., Dalton Trans., 2016, vol. 45, p. 9279.

    Article  CAS  PubMed  Google Scholar 

  41. Yang, L., Wang, X., Zhu, M., et al., Inorg. Chem. Front., 2019, vol. 6, p. 2142.

    Article  CAS  Google Scholar 

  42. Zhang, S., Mo, W., Yin, B., et al., Dalton Trans., 2018, vol. 47, p. 12393.

    Article  CAS  PubMed  Google Scholar 

  43. Liu, C., Li, M., Zhang, Y., et al., Eur. J. Inorg. Chem., 2019, vol. 24, p. 2940.

    Article  CAS  Google Scholar 

  44. Wang, R., Wang, H., Wang, J., et al., CrystEngComm, 2020, vol. 22, p. 2998.

    Article  CAS  Google Scholar 

  45. Katoh, K., Yasuda, N., Damjanović, M., et al., Chem. A Eur. J., 2020, vol. 26, p. 4805.

    Article  CAS  Google Scholar 

  46. Gonzalez, J.F., Montigaud, V., Saleh, N., et al., Magnetochemistry, 2018, vol. 4, p. 39.

    Article  CAS  Google Scholar 

  47. Lim, K.S., Kang, D.W., Song, J.H., et al., Dalton Trans., 2017, vol. 46, p. 739.

    Article  CAS  PubMed  Google Scholar 

  48. Silva, M.R., Martín-Ramos, P., Coutinho, J.T., et al., Dalton Trans., 2014, vol. 43, p. 6752.

    Article  CAS  Google Scholar 

  49. Gavrikov, A.V., Efimov, N.N., Dobrokhotova, Zh.V., et al., Dalton Trans., 2017, vol. 46, p. 11806.

    Article  CAS  PubMed  Google Scholar 

  50. Liu, J.-L., Yuan, K., Leng, J.-D., et al., Inorg. Chem., 2012, vol. 51, p. 8538.

    Article  CAS  PubMed  Google Scholar 

  51. Soussi, K., Jung, J., Pointillart, F., et al., Inorg. Chem. Front., 2015, vol. 2, p. 1105.

    Article  CAS  Google Scholar 

  52. Kobayashi, F., Ohtani, R., Nakamura, M., et al., Inorg. Chem., 2019, vol. 58, no. 11, p. 7409.

    Article  CAS  PubMed  Google Scholar 

Download references

ACKNOWLEDGMENTS

The study was carried out using the research equipment of the Center for Collective Use of Physical Investigation Methods of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Funding

The synthesis and investigation of complexes I and II were supported by the Russian Science Foundation (grant no. 16-13-10407); the synthesis and investigation of complexes III and IV were supported by the Russian Foundation for Basic Research (grant no. 18-33-20155). Elemental analysis was performed within the state assignment for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences.

Author information

Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    S. P. Petrosyants, K. A. Babeshkin, A. B. Ilyukhin & N. N. Efimov

Authors
  1. S. P. Petrosyants
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. K. A. Babeshkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. B. Ilyukhin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to S. P. Petrosyants or K. A. Babeshkin.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by Z. Svitanko

Supplementary Information

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Petrosyants, S.P., Babeshkin, K.A., Ilyukhin, A.B. et al. Molecular Magnets Based on Mononuclear Aqua and Aqua-Chloro Lanthanide (Tb, Dy, Er, Yb) Complexes with Bipyridine. Russ J Coord Chem 47, 165–173 (2021). https://doi.org/10.1134/S1070328421030039

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328421030039

Keywords: