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The trisodium monohydrogen-nitrilo-tris-methylenephosphonato-hydroxylaminato-nitrosyl-molybdate octahydrate Na3[Mo(NO)(NH2O){N(CH2PO3)3H}] · 8H2O: Synthesis, structure, and nature of coordination bond of transition metal with non-innocent ligand

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Abstract

The sodium salt of heteroleptic molybdenum complex with nitrilotris(methylenephosphonic) acid (NTP), hydroxylamine, and nitrogen(II) oxide Na3[Mo(NO)(NH2O){N(CH2PO3)3H}]· 8H2O was synthesized, isolated, and studied (space group P21/c, Z = 4, a = 9.7385(2), b = 10.2542(2), c =21.6517(3) Å, β = 93.7060(10)°). The nitrilotris(methylenephosphonate) ion is monoprotonated at the PO3 group. The nitrogen atom is deprotonated and coordinates the Mo atom; the NTP denticity is 4. Hydroxylamine is ionized according to the acid type and is bidentate. The Mo–NO group is almost linear (176.31(19)° angle; Mo–N, 1.7599(13) Å; ν(N–O), 1756 cm–1), the electron density distribution attests to the formation of an Mo–N π-bond. The Mo coordination polyhedron is a distorted pentagonal bipyramid. Two Na ions are coordinated at the vertices of a distorted octahedron and the third one forms a distorted tetrahedral geometry. (CIF file CCDC no. 1543700.)

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Authors and Affiliations

  1. Lobachevsky State University of Nizhny Novgorod, Nizhny Novgorod, 603950, Russia

    N. V. Somov

  2. Udmurt State University, Izhevsk, Udmurtiya, 426034, Russia

    F. F. Chausov, R. M. Zakirova, I. V. Fedotova & N. V. Lomova

  3. Physical-Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk, 426000, Russia

    F. F. Chausov, N. V. Lomova & I. N. Shabanova

  4. Institute of Mechanics, Ural Branch, Russian Academy of Sciences, Izhevsk, 426067, Russia

    V. G. Petrov, M. A. Shumilova & D. K. Zhirov

Authors
  1. N. V. Somov
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  2. F. F. Chausov
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  3. R. M. Zakirova
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  4. I. V. Fedotova
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  5. N. V. Lomova
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  6. I. N. Shabanova
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  9. D. K. Zhirov
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Correspondence to N. V. Somov.

Additional information

Original Russian Text © N.V. Somov, F.F. Chausov, R.M. Zakirova, I.V. Fedotova, N.V. Lomova, I.N. Shabanova, V.G. Petrov, M.A. Shumilova, D.K. Zhirov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 12, pp. 765–774.

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Somov, N.V., Chausov, F.F., Zakirova, R.M. et al. The trisodium monohydrogen-nitrilo-tris-methylenephosphonato-hydroxylaminato-nitrosyl-molybdate octahydrate Na3[Mo(NO)(NH2O){N(CH2PO3)3H}] · 8H2O: Synthesis, structure, and nature of coordination bond of transition metal with non-innocent ligand. Russ J Coord Chem 43, 864–873 (2017). https://doi.org/10.1134/S1070328417120090

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  • DOI: https://doi.org/10.1134/S1070328417120090

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