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Yttrium tris-propionate monohydrate: Synthesis, crystal structure, and thermal stability

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Abstract

The complex [Y(Prop)3(H2O)]∞ (I) was prepared by treating yttrium carbonate, acetate, or acetylacetonate hydrates with propionic acid and characterized by the data of elemental analysis, IR spectroscopy, X-ray diffraction, and thermal analysis in air. Complex I has a polymeric layered structure with clear-cut structure-forming dimeric groups bridged by bidentate ligands. Only van der Waals interactions occur between the adjacent polymeric layers. In air, yttrium propionate monohydrate I is completely converted to the oxide at 600°C.

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Authors and Affiliations

  1. Moscow State University, Moscow, 119899, Russia

    I. A. Martynova, D. M. Tsymbarenko & N. P. Kuz’mina

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  1. I. A. Martynova
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  2. D. M. Tsymbarenko
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  3. N. P. Kuz’mina
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Correspondence to I. A. Martynova.

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Original Russian Text © I.A. Martynova, D.M. Tsymbarenko, N.P. Kuz’mina, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 8, pp. 494–500.

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Martynova, I.A., Tsymbarenko, D.M. & Kuz’mina, N.P. Yttrium tris-propionate monohydrate: Synthesis, crystal structure, and thermal stability. Russ J Coord Chem 40, 565–570 (2014). https://doi.org/10.1134/S1070328414080077

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  • DOI: https://doi.org/10.1134/S1070328414080077

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