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Synthesis and magnetic properties of a new binuclear copper(II) complex with naphthalato-bridged ligand

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Abstract

To utilized a bridged-ligand of 1,8-naphthalate dianion (NAPH) as building block by self-assembly technology, a new binuclear copper(II) compound [Cu2(μ-NAPH)2(DMF)4(H2O)2] (I) has been constructed and structurally characterized by X-ray crystallography. Complex I crystallizes in monoclinic, space group C2/c, with a = 17.822(9), b = 9.964(5), c = 23.194(11) Å and β = 102.385(5)°. Magnetic measurements confirm that I presents a very weak antiferromagnetic interaction between the paramagnetic ions.

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Authors and Affiliations

  1. Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, P.R. China

    S. Ren, P. Xia, B. Ma, Y. F. He, Y. Yang, M. Y. Tang & S. L. Ma

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  1. S. Ren
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  2. P. Xia
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  3. B. Ma
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  4. Y. F. He
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  5. Y. Yang
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  6. M. Y. Tang
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  7. S. L. Ma
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Correspondence to S. Ren.

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Ren, S., Xia, P., Ma, B. et al. Synthesis and magnetic properties of a new binuclear copper(II) complex with naphthalato-bridged ligand. Russ J Coord Chem 39, 579–582 (2013). https://doi.org/10.1134/S1070328413070105

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  • DOI: https://doi.org/10.1134/S1070328413070105

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